ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Polarized neutron diffraction has been used to investigate the spin delocalization from the high-spin Fe(III) sites to the low-spin Fe(II) in deuteriated Prussian Blue, Fe4[Fe(CN)6]3 · xD2O. Measurements of the 111, 200, and 400 reflections were made on a powdered sample at 3 K and 4.8 T using a neutron wavelength of 1.074 Å. The expectation value of S at the Fe(II) site is - 0.008 ± 0.028 corresponding to an upper limit of about 5% of an electron for the spin delocalization.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19800630115
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