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  • 1
    Call number: S 05.0339(32)
    In: Initial reports of the deep sea drilling project
    Type of Medium: Series available for loan
    Pages: xxviii, 980 S. : zahlr. graph. Darst.
    Language: English
    Location: A 18 - must be ordered
    Branch Library: GFZ Library
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  • 2
    Call number: S 05.0339(41)
    In: Initial reports of the deep sea drilling project
    Type of Medium: Series available for loan
    Pages: xxvi, 1259 S. : zahlr. graph. Darst. + 1 Kt.
    Language: English
    Location: A 18 - must be ordered
    Branch Library: GFZ Library
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  • 3
    Publication Date: 2021-07-09
    Description: EXTRACT (SEE PDF FOR FULL ABSTRACT):Laminated sediments are preserved in upper Pleistocene sections of cores collected on the continental slope at water depths within the present oxygen-minimum zone from at least as far north as the Klamath River and as far south as Point Sur. Comparison of sediment components in the laminae with those delivered to sediment traps as pelagic marine "snow" show the dark/light lamination couplets are indeed annual (varves). ... The presence of carbon-, sulfur-, and metal-rich sediments, as well as lack of bioturbation, all support the theory that the oxygen-minimum zone in the northeastern Pacific Ocean was more intense - in fact, anoxic - during the late Pleistocene in response to greater coastal upwelling and higher organic productivity.
    Keywords: Earth Sciences ; Oceanography ; PACLIM
    Repository Name: AquaDocs
    Type: conference_item
    Format: application/pdf
    Format: application/pdf
    Format: 187-203
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  • 4
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    In:  http://aquaticcommons.org/id/eprint/15568 | 8 | 2014-11-06 00:55:50 | 15568
    Publication Date: 2021-07-08
    Description: Upper Pleistocene sediments on the continental slope off Northern California contain alternations of varves and bioturbation produced by fluctuations in intensity of the coastal upwelling system. Stable isotopic analyses of benthic Foraminifera across a particularly well developed varve/bioturbation sequence deposited ~26,000 years ago reveal rapid shifts of ~0.25‰ in δ18O and ~0.4‰ in δ13C. The δ18O shift occurs within a varved section. Based on varve counts, the isotopic change occurred in less than 100 years. Timing and magnitude of the shift coincide with similar shifts observed in almost all other high-resolution δ18O records that have been interpreted as primarily representing global in-volume fluctuations.
    Keywords: Chemistry ; Earth Sciences ; Oceanography ; PACLIM
    Repository Name: AquaDocs
    Type: conference_item
    Format: application/pdf
    Format: application/pdf
    Format: 83-86
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  • 5
    Publication Date: 2022-05-25
    Description: © The Author(s), 2016. This is the author's version of the work and is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Earth and Planetary Science Letters 453 (2016): 152-160, doi:10.1016/j.epsl.2016.08.007.
    Description: Eruption rates at the mid–ocean ridges (MORs) are believed to strongly control the morphology and length of lava flows emplaced along the ridge axis, and thus the structure and porosity of the upper oceanic crust. Eruption rate also represents one of the few tools to gain insight into the driving pressures within sub-ridge magmatic systems. As eruption rate is inferred to vary systematically along the global mid-ocean ridge, understanding of how to assess eruption rate in submarine systems and how it maps to observable features of the ridge axis would provide a powerful tool to understand Earth's largest magmatic system. Eruption rates at MORs are poorly constrained, however, because of a lack of direct observations, preventing the duration of an eruption to be quantified. This study uses decompression experiments of MORB samples and numerical modeling of CO2 degassing to reconstruct the timescales for magma ascent and lava emplacement during the 2005–06 eruption of the East Pacific Rise at ca. 9°51’N. Samples collected from the lava flow are all supersaturated in dissolved CO2 contents, but CO2 decreases with distance from the vent, presumably as a consequence of progressive CO2 diffusion into growing bubbles. Samples collected at the vent contain ~105 vesicles per cm3. Pieces of these samples were experimentally heated to 1225°C at high pressure and then decompressed at controlled rates. Results, plus those from numerical modeling of diffusive bubble growth, indicate that magma rose from the axial magma chamber to the seafloor in ≤1 hour and at a rate of ≥2–3 km hr-1. Our modeling, as validated by experimental decompression of MORB samples with ~106 vesicles cm-3, also suggests that CO2 degassed from the melt within ~10–100 minutes as the vesicular lava traveled ~ 1.7 km along the seafloor, implying a volumetric flow rate on order of 103–4 m3 s-1. Given an ascent rate of ≥0.2 m s-1, the width of a rectangular dike feeding the lava would have been ~1–2 meters wide. MORB samples from the Pacific ridge are generally more supersaturated in dissolved CO2 than those from slower spreading Atlantic and Indian ridges. Our results suggest that Pacific MORBs ascend to the seafloor faster than Atlantic or Indian MORBs
    Description: This project was partially funded by a grant to J.E.G. from the U.S. National Science Foundation (OCE-1333882).
    Description: 2017-08-27
    Keywords: Mid-ocean ridge ; Basalt ; Eruption rate ; Bubble ; H2O ; CO2
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 82 (1960), S. 4905-4908 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Biochemistry 2 (1963), S. 689-696 
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 7780-7786 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Charge exchange and dissociative ionization cross sections are reported for N+–CO2 and N+2–CO2 collisions at center-of-mass energies between 2 and 40 eV. Product ion kinetic energies are measured using time-of-flight techniques. Energy resonance considerations based on CO2 ionization Franck–Condon factors predict charge exchange to be slow for both of these reaction pairs. The N+–CO2 charge exchange, however, exhibits a large cross section and proceeds about one order of magnitude faster than the N+2–CO2 charge exchange. The formation of CO+ in N+–CO2 collisions is reported, while no dissociative ionization products are observed in the N+2–CO2 system.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 1117-1125 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Charge exchange and hydrogen atom pickup cross sections, and product ion time-of-flight measurements are reported for N+2 –H2O(D2O) collisions at center-of-mass collision energies ranging between 1 and 15 eV. No isotope effect is detected for the charge exchange branch, while a significant isotope effect is observed for the atom pickup reaction. Throughout the measured energy range, the time-of-flight measurements show that the H2O+(D2O+) charge exchange product is produced with near-thermal energy in the laboratory frame, implying little or no momentum transfer. The charge exchange reaction products are therefore formed with internal energy comparable to the exothermicity of the reaction (2.96 eV). The atom pickup ion product velocity distributions and the atom pickup isotope effect are consistent with a spectator stripping mechanism.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 3196-3206 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The reaction of H2O+ with H2O is studied using a longitudinal geometry double mass spectrometer in the collision energy range Ec.m.=0.5–25 eV. Cross sections are reported for oxonium ion (H3O+) production and the symmetric charge exchange. Isotopic substitution is used to discern the product branches, including the separation of the two channels for oxonium ion production: (i) proton transfer to the target molecule; and (ii) atom pickup by the primary ion. The largest branching ratio is observed for the charge exchange channel, where no isotope effect is detected in the investigated energy range. Proton transfer exhibits the second largest branching ratio and accounts for more than 90% of the oxonium ion production throughout the measured energy range. The proton transfer cross section is dependent on isotopic substitution, while the atom pickup channel is too weak to make a distinct statement on its isotopic behavior. Product ion energies, determined by time-of-flight measurements, are also reported for each of the three channels. These measurements show that most (〉95%) of the oxonium ions are formed via a direct, spectator stripping type mechanism while a small amount of reaction products exhibit considerable internal excitation. The charge exchange secondary ions are primarily formed at near-thermal energies in the laboratory frame. Small amounts of high laboratory energy product ions are also observed which at least partly originate through the dissociation of excited oxonium ions.
    Type of Medium: Electronic Resource
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