ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary The organopalladium(II) complexes: Pd(2,4,6-C6F3H2)2L2 [L=triphenylphosphine(PPh3), methyldiphenylphosphine(PPh2Me), dimethylphenylphosphine-(PPhMe2) or pyridine(py); L2=1,2-bis(diphenylphosphino)ethane(dpe), 2,2′-bipyridine(bipy), 1, 10-phenanthroline(phen) or ethylenediamine(en)] have been prepared by addition of the appropriate compound to the THF-dioxane solution resulting from the arylation of potassium tetrachloropalladate(II) with (2,4,6-C6F3H2)MgBr. The i.r. data suggest that the py and PPhMe2 compounds are thecis-isomers, whereas the PPh3 and PPh2Me compounds have thetrans configuration.1H- and19F-n.m.r. data for the compounds are reported.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01022339
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