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  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Physica C: Superconductivity and its applications 235-240 (1994), S. 705-706 
    ISSN: 0921-4534
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Genetics 14 (1980), S. 145-178 
    ISSN: 0066-4197
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Biology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Soil use and management 10 (1994), S. 0 
    ISSN: 1475-2743
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract. Dryland salinity in the Mt Lofty Ranges, South Australia has developed as a result of native vegetation being replaced with pastures that use less water. Groundwaters have risen and mobilized ions (sodium, chloride, sulphate and iron) stored within deeply weathered micaceous sandstones and schists. Salinity resulting from sodium chloride is common in agricultural catchments around Australia, but saline sulphidic soils (with sulphate and iron) have only been studied in South Australia. Salinity is also associated with waterlogging and secondary sodicity. The amelioration of dryland salinity and waterlogging involves management of whole catchments, not just the area that is currently saline. It is imperative that all processes operating in saline catchments and their interactions are clearly understood.Salinity, waterlogging, sodicity, sulphidization and water erosion were studied in four saline sub-catchments in the Mt Lofty Ranges. Grey (bleached) and yellow mottles (iron depletions) or black and red stains (iron concentrations) develop under certain conditions of water saturation, salinization, sulphidization, sodification and water erosion in surface and subsurface horizons. The amounts of these diagnostic features were used to develop a farm planning key for managing saline catchments in the Mt Lofty Ranges. Using soil diagnostic features, soil-water processes in saline catchments are easily identified by farmers and land managers. Management options (e.g. fencing, tree planting and drainage) are then targeted to specific soils and can be easily incorporated by agricultural advisers into farm management plans. We recommend that soil diagnostic features which help predict the onset of land degradation be used in the production of land capability maps for farm planning purposes.
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  • 4
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: The red and yellow colours of ferralitic soils in the tropics have for long intrigued pedologists. We have investigated the upward yellowing in a 10-m thick profile representative of the Ferralsols of the plateaux of the Manaus region of Brazil. We determined changes in the nature and crystal chemistry of their Fe oxides by optical and Mössbauer spectroscopy as well as Rietveld refinement of X-ray diffraction patterns. We attribute the upward yellowing of the soil to a progressive transformation of the Fe oxides at nearly invariant iron contents. Aluminium in contrast is strongly mobilized in the uppermost clay-depleted topsoil where there is preferential dissolution of kaolinite and crystallization of gibbsite. Haematite decreases from 35 to 10% of the Fe oxides from the bottom to the top of the profile and the particles become smaller (75–10 nm). Its Al for Fe-substitution remains almost unchanged (10–15 mol %). The average Al-substitution rate of goethite increases from 25 to 33 mol %, and its mean crystal diameter remains in the range 20–40 nm. The proportion of Al-rich goethite (33 mol %) increases at the expense of less Al-substituted Fe oxides (haematite and goethite). This conversion with restricted transfer of iron means that the amount of Al stored in Fe oxides gradually increases. Kaolinite, haematite and Al-poor goethite are thus witnesses of earlier stages of ferralitization of the soil. In contrast, Al-rich goethite and gibbsite initiate the alitization (or bauxitization) of the soil. They correspond to the last generation of soil minerals, which most likely reflects the present-day weathering conditions. The progressive replacement of kaolinite, haematite and Al-poor goethite by new generations of Al-rich goethite and gibbsite attests to greater activities of water and aluminium and smaller activity of aqueous silica in the topsoil than in the subsoil. We interpret this as a consequence of longer periods of wetting in the topsoil that could result from soil aging, more humid climate or both.
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  • 5
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Morphological, geochemical and mineralogical studies were carried out in a representative soil catena of the low-elevation plateaux of the upper Amazon Basin to interpret the steps and mechanisms involved in the podzolization of low-activity clay soils. The soils are derived from Palaeozoic sandstones. They consist of Hydromorphic Podzols under tree savannah in the depressions of the plateaux and predominantly of Acrisols covered by evergreen forest elsewhere.Incipient podzolization in the uppermost Acrisols is related to the formation of organic-rich A and Bhs horizons slightly depleted in fine-size particles by both mechanical particle transfer and weathering. Weathering of secondary minerals by organic acids and formation of organo-metallic complexes act simultaneously over short distances. Their vertical transfer is limited. Selective dissolution of aluminous goethite, then gibbsite and finally kaolinite favour the preferential cheluviation of first Fe and secondly Al. The relatively small amount of organo-metallic complexes produced is related to the quartzitic parent materials, and the predominance of Al over Fe in the spodic horizons is due to the importance of gibbsite in these low-activity clay soils.Morphologically well-expressed podzols occur in strongly iron-depleted topsoils of the depression. Mechanical transfer and weathering of gibbsite and kaolinite by organic acids is enhanced and leads to residual accumulation of sands. Organo-metallic complexes are translocated in strongly permeable sandy horizons and impregnate at depth the macro-voids of embedded soil and saprolite materials to form the spodic Bs and 2BCs horizons. Mechanical transfer of black particulate organic compounds devoid of metals has occurred later within the sandy horizons of the podzols. Their vertical transfer has formed well-differentiated A and Bh horizons. Their lateral removal by groundwater favours the development of an albic E horizon. In an open and waterlogged environment, the general trend is therefore towards the removal of all the metals that have initially accumulated as a response to the ferralitization process and have temporarily been sequestrated in organic complexes in previous stages of soil podzolization.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    European journal of soil science 53 (2002), S. 0 
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: The soils and sediments of the uplands in the Manaus region are described and analysed along a representative cross-section. There are two broad types of features, lateritic and redoximorphic. Their formation is linked to two main processes acting under contrasted hydrological regimes. The first process, acting under well-drained conditions, is lateritization. It has transformed strongly weathered sediment into soil and led to depletion of silica (mainly quartz) as well as to relative accumulation of both kaolinite and iron oxides (haematite and goethite). Crystallographic changes observed in the latter have resulted from alternating dissolution and crystallization cycles without significant transfer of iron and alumina. However, in the uppermost soil, dissolution of kaolinite has prevailed over crystallization, leading to depletion of clay and the formation of tiny crystals of gibbsite disseminated throughout the groundmass. The second process results from the development of reducing conditions in groundwater giving redoximorphic features in lateritic soils and sediments. In the sediments, iron has been depleted by regional aquifers to form a pallid zone. In the soil, large amounts of iron and minor amounts of alumina, mainly from aluminous goethite, have been mobilized at first in small patches, which with further mobilization and vertical transfer of these elements have increased in size and have led to the formation of bleached horizons over thin iron pans. Iron has crystallized predominantly as haematite in the iron pans and alumina as large crystals of gibbsite in soil voids. Formation of impervious iron pans holds up fluctuating perched groundwater in the overlying horizons depending on rainfall events.Neotectonic events (formation of uplifted blocks and small grabens) have markedly altered the hydrological regimes. In the uplifted blocks, the soil has been deeply truncated and iron loss has been checked in the uppermost sediment. By contrast, mobilization of iron has been initiated at various places in the soil of the small grabens. In this way tectonic events have checked mobilization of iron in sediments but activated it in soils, leaving spectacular fingerprints on the landscape.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 4777-4782 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The luminescence spectra of fully oxidized porous silicon show two broad bands and one vibronic structure between 2 and 3.3 eV, all excited at 340 or 275 nm (3.65 and 4.51 eV). Two of these structures have not been described previously. Interestingly, these emissions are found in other forms of amorphous or disordered silica with high specific surfaces: frosted silica glass, silica gel, even various natural opals. These emissions disappear when the surface is passivated. They are, therefore, attributed to surface-related defects. The vibronic structure involves a nearly free SiO4 tetrahedron. Another vibronic structure found only in some opals is attributed to the uranyl group. © 2001 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Journal of Organometallic Chemistry 460 (1993), S. C25-C27 
    ISSN: 0022-328X
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 0022-328X
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Journal of Organometallic Chemistry 460 (1993), S. C25-C27 
    ISSN: 0022-328X
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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