ISSN:
1600-5368
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The title compound, [Ni(C2H6OS)6](NO3)2·2C2H6OS, comprises centrosymmetric [Ni(dmso)6]2+ cations, nitrate anions and non-coordinated dimethyl sulfoxide solvent molecules. The octahedral geometry of the cation is very regular, with Ni—O interatomic distances and O—Ni—O interatomic angles falling within narrow ranges 2.0485 (9)–2.0665 (9) Å and 89.12 (4)–93.27 (4)°, respectively. Two weak C—H...O hydrogen-bonding contacts link cations and anions to form a chain which lies along the [111] direction.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S1600536801016403
Permalink