ALBERT

Description: Author(s): A. C. Walters, C. A. Howard, M. H. Upton, M. P. M. Dean, A. Alatas, B. M. Leu, M. Ellerby, D. F. McMorrow, J. P. Hill, M. Calandra, and F. Mauri The low-energy phonons of two different graphite intercalation compounds (GICs) have been measured as a function of temperature using inelastic x-ray scattering (IXS). In the case of the non-superconductor BaC 6 , the phonons observed are significantly higher (up to 20%) in energy than those predicted... [Phys. Rev. B 84, 014511] Published Mon Jul 25, 2011

Description: Nature Physics 13, 962 (2017). doi:10.1038/nphys4190 Authors: M. E. Zayed, Ch. Rüegg, J. Larrea J., A. M. Läuchli, C. Panagopoulos, S. S. Saxena, M. Ellerby, D. F. McMorrow, Th. Strässle, S. Klotz, G. Hamel, R. A. Sadykov, V. Pomjakushin, M. Boehm, M. Jiménez–Ruiz, A. Schneidewind, E. Pomjakushina, M. Stingaciu, K. Conder & H. M. Rønnow The study of interacting spin systems is of fundamental importance for modern condensed-matter physics. On frustrated lattices, magnetic exchange interactions cannot be simultaneously satisfied, and often give rise to competing exotic ground states. The frustrated two-dimensional Shastry–Sutherland lattice realized by SrCu2(BO3)2 (refs ,) is an important test case for our understanding of quantum magnetism. It was constructed to have an exactly solvable 2-spin dimer singlet ground state within a certain range of exchange parameters and frustration. While the exact dimer state and the antiferromagnetic order at both ends of the phase diagram are well known, the ground state and spin correlations in the intermediate frustration range have been widely debated. We report here the first experimental identification of the conjectured plaquette singlet intermediate phase in SrCu2(BO3)2. It is observed by inelastic neutron scattering after pressure tuning to 21.5 kbar. This gapped singlet state leads to a transition to long-range antiferromagnetic order above 40 kbar, consistent with the existence of a deconfined quantum critical point.

Description: Bluegill sunfish use intermittent propulsion during volitional swimming. The function of this propulsive mode during routine swimming has not been well quantified. At low speeds, propulsive cycle frequencies and amplitudes were constant, and average speed and power output were controlled by modulating coasting duration. This fixed-gear gait may accommodate muscle level constraints on power production. At higher speeds bluegills switched to a mixed power-modulation strategy, increasing speed and power through increased propulsive cycle frequency and reduced coasting time.

Description: Hafnium diboride-silicon carbide and zirconium diboride-silicon carbide composites are potential materials for high temperature leading edge applications on reusable launch vehicles. In order to establish material constants necessary for evaluation of in-situ fracture, bars fractured in four point flexure were examined using fractographic principles. The fracture toughness was determined from measurements of the critical crack sizes and the strength values, and the crack branching constants were established to use in forensic fractography of materials for future flight applications. The fracture toughnesses range from about 13 MPam (sup 1/2) at room temperature to about 6 MPam (sup 1/2) at 1400 C for ZrB2-SiC composites and from about 11 MPam (sup 1/2) at room temperature to about 4 MPam (sup 1/2) at 1400 C for HfB2-SiC composites.

Description: The Thermal Protection Materials and Systems Branch at NASA Ames Research Center is involved in the development of a class of refractory oxidation-resistant diboride composites termed Ultra High Temperature Ceramics or UHTCs. These composites have good high temperature properties making them candidate materials for thermal protection system (TPS) applications. The current research focuses on improving processing methods to develop more reliable composites with enhanced thermal and mechanical properties. This presentation will concentrate on the processing of ZrB2/SiC composites. Some preliminary mechanical properties and oxidation data will also be presented.

Description: HfB2 and ZrB2 composites containing SiC are known to have good thermal shock and configurational stability at elevated temperatures. These are promising ultra-high temperature ceramics (UHTCs) for use on the sharp leading edges of next generation space vehicles. Sharp leading edges on these vehicles will need to: withstand repeated exposures to temperatures 〉 2200 C in oxidizing environments; have good thermal shock and ablation resistance; and withstand the mechanical stress of launch and reentry. The HfB2/SiC composite is currently undergoing processing improvements in an effort to better the performance of a material that has been studied for approx. 35 years. The potential for HfB2/SiC composites to meet the requirements of hypersonic flight depends on controlling processing techniques. This presentation will focus on understanding processing steps now being undertaken to optimize the material properties of HfB2/SiC composites at NASA Ames Research Center. Correlation between processing techniques and microstructure will be shown. Preliminary oxidation studies will also be discussed.

Description: Materials with improved properties are needed for thermal protection of next generation space vehicles. Sharp leading edges on these vehicles will have to withstand exposure to high temperatures (〉 2200 C or 4000 F) and severe thermal cycling in both neutral and oxidizing environments. These extreme conditions will require materials that possess superior oxidation resistance, low creep, and excellent thermal shock properties. This presentation will first discuss the system requirements for thermal protection of advanced space vehicles and then show how they are driving development of new materials systems. The presentation will focus on ultrahigh temperature ceramics (UHTCs) that are promising candidates for such applications. ZrB2 and HfB2 and composites of those ceramics with SiC are two particular families of UHTCs that are currently under development for sharp leading edges. These ceramics are appealing because their melting temperatures are 3245 C (5873 F) for ZrB2 and 3380 C (6116 F) for HfB2 and because they may form protective, oxidation resistant coatings in use. The mechanical properties of the UHTCs are strongly dependent on phase purity and the processing route used to make them, both of which factors are being actively investigated. For example, oxide impurities could form glassy grain boundary phases that soften at high temperatures and make the ceramic susceptible to creep deformation. Results from scanning and transmission electron microscopic studies of the UHTCs have shown how their processing can be improved to give better properties. This presentation will discuss the UHTC characterization results in some detail, focusing particularly on the structure and composition of the ceramic grain boundaries. The presentation will conclude with some remarks on how the properties of these promising UHTCs can be further improved and how they might be made more economically.

Description: NASA is anticipated to commission the next Planetary Science Decadal Survey (PSDS) with preparation expected in early calendar year 2020. The new PSDS will outline the priorities of science missions for the decade spanning 2023-2032. For the previous PSDS, the science and technology communities have been invited to submit white papers to the PSDS sub-panels as background information to guide the PSDS recommendations. The National Research Council has previously stated that white papers that represent the opinion of many authors from different institutions carried more significant and weight, and the recommendations from the previous PSDS attempted to reflect more of a consensus opinion.In 2009, a total of 4 white papers were submitted to the PSDS panels regarding thermal protection system (TPS) readiness for missions, as well as one on TPS instrumentation. The TPS readiness papers were co-authored by 90 individuals from many institutions. These white papers surveyed the TPS materials for both forebody and afterbody of a probe and analyzed the suitability of materials for missions to each destination. In addition, each paper outlined the ground testing required and ongoing technology development. Recommendations were provided for further technology development and ground test capability in order to fulfill future missions. Planning for the next PSDS: Many improvements and changes have occurred in the past 10 years with regard to TPS materials and instrumentation. New materials have been developed and tested, such as the high density material Heatshield for Extreme Entry Environment Technology (HEEET), and new capabilities for ground testing for high heating and high pressures have been added such as the 3 nozzle at the Ames arc jet. NASA has also flown several TPS instrumentation suites, such as MEDLI and EFT-1.In order to provide the PSDS sub-panels with the most current information about the state-of-the-art suit-ability for TPS materials for entry missions, we are be-ginning to update and draft new white papers. We will present the outline for material to be covered in the white papers, and we invite all IPPW attendees to parti-ciate in co-authoring these papers.