ISSN:
0749-1581
Keywords:
Electrochemistry
;
Continuous flow
;
13C NMR spectroscopy
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The anodic conversion of 2,4,6-tri-tert-butylphenol in methanol, leading to 2,4,6-tris(1,1-dimethylethyl)-4-methoxy-2,5-cyclohexadien-1-one, has been followed by two types of 13C NMR experiments: (a) a static procedure, inserting the electrodes directly into a rotating NMR tube and (b) a continuous flow procedure, combining electrochemical and NMR flow cells. During electrolysis the resolution of the 13C NMR spectra decreased in the static procedure owing to magnetic field gradients. In the flow procedure the resolution was comparable with that of routine spectra.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260251017
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