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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Geophysical journal international 126 (1996), S. 0 
    ISSN: 1365-246X
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Greigite of variable purity has been synthesized hydrothermally at ∼ 140°C by injecting a Mohr's salt solution into a sodium sulphide solution containing dissolved zerovalent sulphur, ageing for 30–960 min and rapidly quenching. Oxygen was rigorously excluded during the synthesis. Scanning electron microscope (SEM) observations yield a grain-size range up to 400 nm. The variable purity was deduced from a varying specific saturation magnetization (3–29 Am2 kg−1). The Mrs/Ms or σrs/σs ratio varies between 0.3 and 0.4, which is indicative of fine-grained greigite, concurring with SEM observations. Hysteresis measurements at low temperatures indicate the presence of grains that are superparamagnetic at room temperature. Coercivity parameters [(BO)c 13–43 mT; (Bo)cr 37–73 mT] are the highest obtained to date for synthetic greigite and compare well with those measured for natural greigite. Ranges for other rock magnetic parameters are discussed. Greigite hysteresis parameters overlap those of magnetite to a large degree. A diagnostic interparametric ratio for greigite is its high σrs/χin ratio; the range of the present greigite is 40–75 kA m−1.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-1626
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences , Physics
    Notes: Summary The results of a magnetic study of two batches of sized natural haematite fractions (from Kadaň, Czech Republic) are reported. One of the sample batches was prepared by ultrasonic micro precision sieving in propanon (acetone), the other in ethanol (alcohol). Surprisingly, the magnetic behaviour of the ethanol-sieved fractions was much softer (e.g. Hcr ≈ ≈ 20 kA/m) as compared with the propanon-sieved fractions (Hcr 〉 200 kA/m). Thermomagnetic measurements suggest a maghemite portion is present in the material used for the preparation of the ethanol-sieved samples. Possible causes of this puzzling behaviour are discussed. However, no definite conclusion can be drawn on the basis of the data presently available.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Studia geophysica et geodaetica 43 (1999), S. 357-375 
    ISSN: 1573-1626
    Keywords: Magnetic mineralogy ; Low-temperature oxidation ; Coercivity ; Magnetite ; Weathering ; Loess ; Paleoclimate ; Quaternary
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences , Physics
    Notes: Abstract Low-temperature oxidation under atmospheric conditions affects the magnetic properties of magnetite in natural rocks: the coercivities of magnetite grains increase and other parameters change accordingly. It was recently shown that heating to 150°C largely removes the effects of low-temperature oxidation (van Velzen and Zijderveld, 1995). Heating may therefore serve as a detection tool for the presence of the effect of low-temperature oxidation. In the present study, a collection of loess and paleosol samples from various loess regions of the world is examined for the influence of low-temperature oxidation. In all samples of the collection a decrease of coercivities was found after heating to 150°C. Generally loess samples were affected to a larger extent than paleosol samples. The original range of remanent coercivities(B cr)of 21-58 mT changed to 20-42 mT after heating. The IRM capacity of the samples decreased from 0 up to 25%. ARM showed changes between a decrease of 10% and an increase of 15%. The grain-size indicative parameter IRM/ARM is considerably influenced by the heating and therefore by low-temperature oxidation. The changes in susceptibility are limited and will not influence the interpretation of large-scale features of the susceptibility record as a paleoclimate proxy. Small variations, however, may be obscured by the varying influence of oxidation in the outcrop, which can significantly modify the rock-magnetic record. Rock-magnetic parameters used to determine magnetic mineral content and grain sizes should be corrected for the effect of low-temperature oxidation. To this end heating to 150°C is recommended. The occurrence of the changes is in itself already an indication for the presence of magnetite. Low-temperature oxidation will not only be due to recent weathering in the outcrop, but also to earlier oxidation processes in the source area, during transport and deposition of the loess and during pedogenesis. Truly fresh sediment samples are only influenced by this earlier oxidation. In that case heating will reveal the degree of ancient low-temperature oxidation, which may be related to climate at the time of deposition and pedogenesis.
    Type of Medium: Electronic Resource
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  • 4
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    PANGAEA
    In:  Supplement to: Razik, Sebastian; Dekkers, Mark J; von Dobeneck, Tilo (2014): How environmental magnetism can enhance the interpretational value of grain-size analysis: A time-slice study on sediment export to the NW African margin in Heinrich Stadial 1 and Mid Holocene. Palaeogeography, Palaeoclimatology, Palaeoecology, 406, 33-48, https://doi.org/10.1016/j.palaeo.2014.04.009
    Publication Date: 2023-03-03
    Description: Sediment dynamics in limnic, fluvial and marine environments can be assessed by granulometric and rock-magnetic methodologies. While classical grain-size analysis by sieving or settling mainly bears information on composition and transport, the magnetic mineral assemblages reflect to a larger extent the petrology and weathering conditions in the sediment source areas. Here, we combine both methods to investigate Late Quaternary marine sediments from five cores along a transect across the continental slope off Senegal. This region near the modern summer Intertropical Convergence Zone is particularly sensitive to climate change and receives sediments from several aeolian, fluvial and marine sources. From each of the investigated five GeoB sediment cores (494-2956 m water depth) two time slices were processed which represent contrasting climatic conditions: the arid Heinrich Stadial 1 (~ 15 kyr BP) and the humid Mid Holocene (~ 6 kyr BP). Each sediment sample was split into 16 grain-size fractions ranging from 1.6 to 500 µm. Concentration and grain-size indicative magnetic parameters (susceptibility, SIRM, HIRM, ARM and ARM/IRM) were determined at room temperature for each of these fractions. The joint consideration of whole sediment and magnetic mineral grain-size distributions allows to address several important issues: (i) distinction of two aeolian sediment fractions, one carried by the north-easterly trade winds (40-63 µm) and the other by the overlying easterly Harmattan wind (10-20 µm) as well as a fluvial fraction assigned to the Senegal River (〈 10 µm); (ii) identification of three terrigenous sediment source areas: southern Sahara and Sahel dust (low fine-grained magnetite amounts and a comparatively high haematite content), dust from Senegalese coastal dunes (intermediate fine-grained magnetite and haematite contents) and soils from the upper reaches of the Senegal River (high fine-grained magnetite content); (iii) detection of partial diagenetic dissolution of fine magnetite particles as a function of organic input and shore distance; (iv) analysis of magnetic properties of marine carbonates dominating the grain-size fractions 63-500 µm.
    Keywords: Center for Marine Environmental Sciences; MARUM
    Type: Dataset
    Format: application/zip, 5 datasets
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  • 5
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    PANGAEA
    In:  Supplement to: Just, Janna; Dekkers, Mark J; von Dobeneck, Tilo; van Hoesel, Annelies; Bickert, Torsten (2012): Signatures and significance of aeolian, fluvial, bacterial and diagenetic magnetic mineral fractions in Late Quaternary marine sediments off Gambia, NW Africa. Geochemistry, Geophysics, Geosystems, 13, Q0AO02, https://doi.org/10.1029/2012GC004146
    Publication Date: 2023-03-03
    Description: Two gravity cores retrieved off NW Africa at the border of arid and subtropical environments (GeoB 13602-1 and GeoB 13601-4) were analyzed to extract records of Late Quaternary climate change and sediment export. We apply End Member (EM) unmixing to 350 acquisition curves of isothermal remanent magnetization (IRM). Our approach enables to discriminate rock magnetic signatures of aeolian and fluvial material, to determine biomineralization and reductive diagenesis. Based on the occurrence of pedogenically formed magnetic minerals in the fluvial and aeolian EMs, we can infer that goethite formed in favor to hematite in more humid climate zones. The diagenetic EM dominates in the lower parts of the cores and within a thin near-surface layer probably representing the modern Fe**2+/Fe**3+ redox boundary. Up to 60% of the IRM signal is allocated to a biogenic EM underlining the importance of bacterial magnetite even in siliciclastic sediments. Magnetosomes are found well preserved over most of the record, indicating suboxic conditions. Temporal variations of the aeolian and fluvial EMs appear to faithfully reproduce and support trends of dry and humid conditions on the continent. The proportion of aeolian to fluvial material was dramatically higher during Heinrich Stadials, especially during Heinrich Stadial 1. Dust export from the Arabian-Asian corridor appears to vary contemporaneous to increased dust fluxes on the continental margin of NW Africa emphasizing that melt-water discharge in the North Atlantic had an enormous impact on atmospheric dynamics.
    Keywords: Center for Marine Environmental Sciences; MARUM
    Type: Dataset
    Format: application/zip, 15 datasets
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  • 6
    Publication Date: 2023-06-27
    Keywords: 409-1; Aluminium; Calcium; Center for Marine Environmental Sciences; DEPTH, sediment/rock; GeoB13602-1; Gravity corer (Kiel type); Iron; Magnesium; Manganese; Maria S. Merian; MARUM; MSM11/2; Phosphorus; Potassium; Rubidium; Silicon; SL; Southern Senegal; Strontium; Sulfur, total; Titanium; X-ray fluorescence (XRF); Zinc
    Type: Dataset
    Format: text/tab-separated-values, 2314 data points
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  • 7
    Publication Date: 2023-06-27
    Keywords: 407-4; Age, comment; Age model; Center for Marine Environmental Sciences; DEPTH, sediment/rock; GeoB13601-4; Gravity corer (Kiel type); Maria S. Merian; MARUM; MSM11/2; SL; Southern Senegal
    Type: Dataset
    Format: text/tab-separated-values, 26 data points
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  • 8
    Publication Date: 2023-06-27
    Keywords: 409-1; after Mullender et al. 1993; Center for Marine Environmental Sciences; DEPTH, sediment/rock; GeoB13602-1; Gravity corer (Kiel type); Magnetization; Maria S. Merian; MARUM; MSM11/2; SL; Southern Senegal; Temperature, technical
    Type: Dataset
    Format: text/tab-separated-values, 9978 data points
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  • 9
    Publication Date: 2023-06-27
    Keywords: 409-1; Age, 14C AMS; Age, comment; Age, dated; Age, dated standard deviation; Calendar age; Center for Marine Environmental Sciences; DEPTH, sediment/rock; GeoB13602-1; Gravity corer (Kiel type); Maria S. Merian; MARUM; MSM11/2; Sample code/label; SL; Southern Senegal
    Type: Dataset
    Format: text/tab-separated-values, 42 data points
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  • 10
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    PANGAEA
    In:  Supplement to: Just, Janna; Heslop, David; von Dobeneck, Tilo; Bickert, Torsten; Dekkers, Mark J; Frederichs, Thomas; Meyer, Inka; Zabel, Matthias (2012): Multi-proxy characterization and budgeting of terrigenous end-members at the NW African continental margin. Geochemistry, Geophysics, Geosystems, 13, Q0AO01, https://doi.org/10.1029/2012GC004148
    Publication Date: 2023-06-27
    Description: Grain-size, terrigenous element and rock magnetic remanence data of Quaternary marine sediments retrieved at the NW African continental margin off Gambia (gravity core GeoB 13602-1, 13°32.71' N, 17°50.96'W) were jointly analyzed by end-member (EM) unmixing methods to distinguish and budget past terrigenous fluxes. We compare and cross-validate the identified single-parameter EM systems and develop a numerical strategy to calculate associated multi-parameter EM properties. One aeolian and two fluvial EMs were found. The aeolian EM is much coarser than the fluvial EMs and is associated with a lower goethite/hematite ratio, a higher relative concentration of magnetite and lower Al/Si and Fe/K ratios. Accumulation rates and grain sizes of the fluvial sediment appear to be primarily constrained by shore distance (i.e., sea-level fluctuations) and to a lesser extent by changes in hinterland precipitation. High dust fluxes occurred during the Last Glacial Maximum (LGM) and during Heinrich Stadials (HS) while the fluvial input remained unchanged. Our approach reveals that the LGM dust fluxes were ~7 times higher than today's. However, by far the highest dust accumulation occurred during HS 1 (~300 g m**-2 yr** -1), when dust fluxes were ~80 fold higher than today. Such numbers have not yet been reported for NW Africa, and emphasize strikingly different environmental conditions during HSs. They suggest that deflation rate and areal extent of HSs dust sources were much larger due to retreating vegetation covers. Beyond its regional and temporal scope, this study develops new, in principle, generally applicable strategies for multi-method end-member interpretation, validation and flux budgeting calibration.
    Keywords: 409-1; Center for Marine Environmental Sciences; GeoB13602-1; Gravity corer (Kiel type); Maria S. Merian; MARUM; MSM11/2; SL; Southern Senegal
    Type: Dataset
    Format: application/zip, 2 datasets
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