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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 56 (1985), S. 1635-1638 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A simple technique to measure simultaneously the diffusion coefficient and the partial vapor pressure of a solute in a homogeneous solid solution is presented. The analysis is based on the mathematical solution of the diffusion equation for a cylindrical system with a solute loss term at the cylinder surface. The magnitude of the loss term is proportional to the solute concentration at the surface. Three zirconium rods, one with 3 at. % Sn, one with 5 at. % Sn, and one with 4 at. % Ti, were treated in vacuum at 1875 K for 7, 5, and 2.5 h, respectively. Results from these specimens indicate that Sn and Ti both diffuse via a vacancy mechanism in β-Zr. Also, the Sn–Zr bonds appear to be much stronger than the Sn–Sn bonds, whereas the Ti–Zr bonds seem to be a little weaker than the Ti–Ti bonds.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-5117
    Keywords: cormorants ; roach ; populations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Breeding cormorants, Phalacrocorax carbo, in Northern Ireland remain seasonally dependent on a coastal environment where they can be censused with accuracy, but numbers in other habitats and at other times of the year are less certain. This study establishes the long term and regional patterns of abundance at breeding and feeding localities, which might in turn be related to diet. Birds were regularly observed and counted at a variety of feeding sites, and some aspects of their breeding success and fledgling diet evaluated at the largest N.Ireland breeding colony. Numbers of breeding birds increased dramatically over a period of eight years but recently show signs of declining. There is likely to be a dynamic relationship between populations of a tapeworm (Ligula intestinalis L.), the numbers of roach (Rutilus rutilus [L.]) and cormorant populations feeding at Lough Neagh, the largest lake in the British Isles. While roach are not a major component in the diet of fledglings, the large numbers of cormorants feeding at the perimeter of L. Neagh suggest that changes in roach populations will affect birds most acutely during or following the winter. We suggest that this might result in a reduction in the proportion of the population volunteering to breed in the subsequent season, but require further data. The longer term effects of one fish species on cormorant populations are unlikely to be critical, since these birds are highly opportunist. In other habitats cormorant numbers are either very stable (estuary) or variable (river) depending on the seasonal and annual availability of their prey. There is no evidence for a systematic seasonal shift in habitat, as suggested by other studies.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 24 (1996), S. 591-596 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A number of binary oxides, sulphide compounds and complex minerals have been analysed by x-ray photoelectron spectroscopy to give the relative intensities of major photoelectron lines. Where possible, compound surfaces were prepared by fracturingin vacuoor in inert gas to avoid contamination. Alternatively, some of these compounds have undergone a mild thermal treatmentin vacuoto remove much of the surface contamination which normally affects such intensity measurements. The experimental line intensity ratios were corrected only by their particular photoelectron cross-section and inelastic mean free paths. For most oxides and complex minerals studied, good agreement is obtained with the expected stoichiometry, particularly when using photoelectron lines of higher kinetic energy. This tends to support the use of a simple background approximation when measuring specifically with those oxides involving non-transition elements. The sulphides studied mostly involved transition metals; agreement between calculated and actual stoichiometry was only modest. Some differences in measured surface stoichiometry occurred as a result of the ambient conditions within which the fracture was made; fracturein vacuoproduced a different S/M ratio than did fracture in an inert gas environment.
    Additional Material: 3 Ill.
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  • 4
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Understanding the mechanisms of hydrogen ingress into pressure tubes fabricated from zirconium-2.5% (w/w) niobium alloy requires knowledge of the hydrogen concentration in the surface oxides, of the oxide/metal interface and in the alloy phase beneath the interface. Secondary ion mass spectrometry (SIMS) has attractive capabilities for detecting hydrogen isotopes in such surface films, but its quantitative response and spatial resolution are controversial for hydrogen because of the strong tendency for the element to migrate, owing to thermal and sputtering effects. High sputter rate conditions have been used here, which result in an improved capability to detect hydrogen in Zr—Nb alloy and ZrO2 down to concentrations of 〈2 × 1017 atoms cm-3 (〈0.1 ppm, w/w). Quantitation of deuterium concentrations has been accomplished by SIMS calibrated using ion implants and, in some cases, verified by nuclear reaction analysis (NRA).
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 7 (1985), S. 105-108 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Auger electron spectroscopy (AES), in conjunction with argon ion sputtering, is frequently used to obtain composition versus depth profiles. Thin film thicknesses may be estimated from such profiles if the argon ion sputtering rate of a particular material is known. For this work, a series of oxide standards was prepared and calibrated with nuclear microanalysis techniques. These standards were then used to calibrate the composition versus depth profiles obtained using AES.
    Additional Material: 4 Ill.
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  • 6
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The nickel-rich superalloys Alloy 600 and Alloy 800 have been corroded in mildly alkaline deuterated aqueous conditions typical of secondary coolant circuits in a nuclear power station. The oxide films and substrates of these alloys have been analysed by imaging SIMS depth profiling, which makes it possible to describe elemental distribution in all three dimensions. The measurement of the distribution of the secondary ions NiO-, FeO- and CrO- appears useful for detailing the behaviour of nickel, iron and chromium within oxidized phases. The measurement of D- distribution outlines the extent of oxide hydration. For Alloy 800, evidence of sodium migration into the grain boundaries of the alloy substrate is found. For Alloy 600, no grain boundary sodium ingress can be identified under comparable corrosion conditions.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 15 (1990), S. 265-272 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Surface oxidation reactions of cobalt, molybdenum and mixed cobalt-molybdenum metals have been investigated using x-ray photoelectron spectroscopy (XPS). The oxide stoichiometries have been determined from XPS intensity measurements. Such quantification has been important in identifying oxide compositions with characteristic XPS spectra. A number of discrete binary molybdenum oxides have been characterized after reactions at 200°C and pressures ranging from 1 atm to 10-6 Pa. At the lowest pressure, the Mo 3d spectra and O/Mo ratios suggest the formation of a molybdenum-oxygen structure with a stoichiometry near unity. By contrast, at higher pressures, oxides that are predominantly MoO2 and MoO3 appear, but other intermediate oxide structures are also identified. Well-defined binary oxides of cobalt can be prepared from cobalt metal after heating in oxygen at different pressures. New binary oxides of cobalt and molybdenum have been generated by the reaction on MoO3 or Co3O4 substrates. Oxidation of a thin film of molybdenum on a Co3O4 substrate has been shown to produce a nearly stoichiometric surface layer of CoMoO4. The procedure could be useful for the production of other ternary oxides of possible interest for use as XPS reference materials.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 11 (1988), S. 441-446 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The thickness of thin natural oxide films formed on silicon, nickel, aluminium, iron, tantalum and zirconium has been measured using nuclear reaction analysis (NRA) and Auger electron spectroscopy (AES) in combination with ion beam sputtering. It is shown that ion beam effects severely limit the use of AES and ion beam sputtering in measuring thin oxide thicknesses. Relatively non-destructive techniques such as NRA or angle-resolved x-ray photoelectron spectroscopy (XPS) provide more reliable information.
    Additional Material: 3 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 17 (1991), S. 757-763 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Hydrogen migration has been followed through the thermally-grown oxide on a Zr-2.5% Nb alloy. A secondary ion mass spectrometer, calibrated for deuterium, was used to measure the concentration as a function of depth into the film. Thin film oxide specimens, grown in steam to ∼1 μm thickness, were heated to 350 °C and exposed to deuterium gas at pressures ranging from 6 × 10-3 to 6 Pa and times from 30 to 870 min. Some irreversible uptake was detected for all exposures using SIMS. At low exposures, the shape of the deuterium concentration profile is Fickian and diffusion coefficients have been calculated. In this low-exposure regime, the effect of temperatures between 280 °C and 350 °C on the diffusion equation has been measured. At longer exposures, the rate of deuterium ingress was sharply curtailed and a more complex diffusion profile was observed. Using Raman spectroscopy during a depth profile, the ZrO2 component of the oxide is found to change from a monoclinic-tetragonal mixture at the oxide surface to a primarily tetragonal oxide near the oxide/metal interface. Such changes in phase probably contribute to the complex deuterium diffusion kinetics observed during the longer exposures of the oxide film to deuterium gas.
    Additional Material: 8 Ill.
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  • 10
    Publication Date: 1977-12-01
    Print ISSN: 1073-5623
    Electronic ISSN: 1543-1940
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Published by Springer
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