ISSN:
1436-5073
Keywords:
titanium determination
;
spectrophotometry
;
extraction
;
liquid ionexchanger
;
ores and aluminium alloys analysis
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A sensitive method for the determination of titanium, based on the formation of a mixed-ligand Ti (IV)-salicylhydroxamic acid-thiocyanate complex and extraction of this into a liquid ion-exchanger phase has been developed. The extract has maximum absorbance at 400–460 nm and the apparent molar absorptivity is 1.8 × 104l · mole−1 · cm−1 at 420 nm. The system obeys Beer's law at 420 nm in the range 0.16–3.20 mg/1 Ti, the detection limit being 0.1 mg/1. The method is found suitable for determination of titanium in aluminium alloys and silicate rocks.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01242891
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