ISSN:
1573-4803
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
Abstract Electron spin resonance linewidths of Co2+ in single-crystal MgO at 9 GHz were examined experimentally and theoretically for a range of Co2+ concentration from 310 to 9900 ppm. In contrast to the behaviour expected from dipolar broadening, the experimental peak-to-peak linewidth for the octed hyperfine lines were about twelve to fifty times less than the calculated dipolar linewidths according to temperature and concentrations. The peak-to-peak linewidths as determined experimentally increase from 0.8 mT at 310 ppm Co2+ to 4.0 mT at 9900 ppm Co2+ at a polar angle θ H= O° and at 20 K. Peak-to-peak linewidths independent of polar angle but strongly dependent on temperature and slightly dependent on concentrations were observed. The ratio of moments M 4 1/4 /M 2 1/2 derived from the experimental data lay between 1.35 to 1.44 and the lineshapes were markedly Lorentzian in the range of temperature measured. The data suggest that Co2+ entered the lattice substitutionally, occupying magnesium sites, that the linewidths were determined, after exchange energy, over the whole concentration range examined and that the exchange energy whose values lay between 6 and 77 GHz, varied linearly with concentration.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00552101
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