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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 49 (1927), S. 2098-2101 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 34 (1962), S. 80-82 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 27 (1955), S. 369-371 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 26 (1954), S. 1008-1011 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 19 (1947), S. 484-487 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 55 (1933), S. 2064-2068 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
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  • 7
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 65 (1943), S. 1606-1607 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 102 (1995), S. 6456-6462 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The time-dependent fluorescence Stokes shift of p,p'-cyano thiomethyl diphenylacetylene in three different alcohols (1-propanol, 1-butanol, and 1-octanol) at room temperature was measured using time-correlated single photon counting and the spectral reconstruction method. These measurements were also performed with the probe in 1-propanol at low temperatures. The observed behavior is consistent with the dynamics of solvation of a polar excited state. As expected, the average solvation time increases with decreasing temperature and is correlated with solvent bulk viscosity down to 180 K. Apparent deviations observed at lower temperatures are attributed to the finite emission lifetime (≈1 ns) of the probe. A significant fast component (〈100 ps) is observed in the dynamic Stokes shift even at temperatures close to the freezing point of 1-propanol. Different mechanisms that could result in such a fast component are discussed. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 27 (1989), S. 0 
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: A reference repository is examined for environmental compliance utilizing minimum performance standards as established by the Nuclear Regulatory Commission and the Environmental Protection Agency. These standards stipulate the amount of time the radionuclides must be retained in the barrier, the acceptable release rates from the barrier, and the acceptable mass release that can be registered at the accessible environment over a 10,000-year time frame. The only natural, or geologic barrier standard specified is a minimum ground-water travel time of 1000 years from the engineered barrier to the accessible environment. Other natural barrier processes including geochemical retardation and mass transfer, dilution, and dispersion are not specified. In attempting to determine the role that these unspecified components must play in order to comply with the mass release standard, we find that their role is minimal to the extent that virtually any rock type that can satisfy the minimum ground-water travel time of 1000 years will satisfy the mass release requirements at the accessible environment. Full compliance with a concentration standard at the accessible environment requires that the nuclides contained within the larger inventories be fully contained with the controlled zone between the engineered barrier and the accessible environment
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 11 (1993), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract Incipient charnockite formation within amphibolite facies gneisses is observed in South India and Sri Lanka both as isolated sheets, associated with brittle fracture, and as patches forming interconnected networks. For each mode of formation, closely spaced drilled samples across charnockite/gneiss boundaries have been obtained and δ13C and CO2 abundances determined from fluid inclusions by stepped-heating mass spectrometry.Isolated sheets of charnockite (c.50 mm wide) within biotite–garnet gneiss at Kalanjur (Kerala, South India) have developed on either side of a fracture zone. Phase equilibria indicate low-pressure charnockite formation at pressures of 3.4 ± 1.0 kbar and temperatures of about 700°C (for XH2O= 0.2). Fluid inclusions from the charnockite are characterized by δ13C values of −8% and from the gneiss, 2 m from the charnockite, by values of −15%. The large CO2 abundances and relatively heavy carbon-isotope signature of the charnockite can be traced into the gneiss over a distance of at least 280 mm from the centre of the charnockite, whereas the reaction front has moved only 30 mm. This suggests that fluid advection has driven the carbon-isotope front through the rock more rapidly than the reaction front. The carbon-front/reaction-front separation at Kalanjur is significantly larger than the value determined from a graphite-bearing incipient charnockite nearby, consistent with the predictions of one-dimensional advection models.Incipient charnockites from Kurunegala (Sri Lanka) have developed as a patchy network within hornblende–biotite gneiss. CO2 abundances rise to a peak near one limb of the charnockite, and isotopic values vary from δ13C of c.−5.5% in the gneiss to −9.5% in the charnockite. The shift to lighter values in the charnockite can be ascribed to the formation of a CO2-saturated partial melt in response to influx of an isotopically light carbonic fluid.Thus, incipient charnockites from the high-grade terranes of South India and Sri Lanka reflect a range of mechanisms. At shallower structural levels non-pervasive CO2 influxed along zones of brittle fracture, possibly associated with the intrusion of charnockitic dykes. At deeper levels, in situ melting occurred under conditions of ductile deformation, leading to the development of patchy charnockites.
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