ISSN:
1434-193X
Keywords:
Aminophosphane
;
Chirality
;
Chromium complexes/ Diastereoselective reactions
;
P ligands
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Chiral α-aminophosphane (α-P-C-N) ligands have been prepared by reversible addition of Ph2PH to tricarbonylchromium benzaldimine complexes (CO)3Cr[η6-o-C6H4(Y)(CH=NR)] (with Y, R = CH3, CH3 or CH2COOCH3; CH3O, CH3 or p-CH3OC6H4; Cl, C6H5), with complete diastereoselectivity. These complexes are stabilized in solution by electron-withdrawing group(s) on the imine.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
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