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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 68 (1990), S. 8-13 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: 3-methyl-4-nitropyridine-1-oxide is an organic material presenting high optical nonlinear behavior especially for second-harmonic generation. Single crystals are obtained by spontaneous nucleation and grown by slow cooling in tetramethoxysilane gel. Coupled phase-matched second-harmonic generation and x-ray topography experiments allow one to relate nonlinear optical performance to crystalline quality.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 87 (2000), S. 3258-3262 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Electro-optic waveguiding polymer devices are very attractive for optical communication systems as a result of simple and potentially low-cost fabrication procedures. Several functions, such as high speed modulation or switching, have been already demonstrated. However, their polarization sensitive response precludes any actual use in optical telecommunication systems. The traditional uniform poling procedure, a prerequisite processing step for electro-optic polymer based devices whereby an electric field is applied at the vicinity of the glass transition temperature resulting in statistical polar orientation of the chromophores, is responsible for polarization sensitivity. By way of different coplanar or sandwich electrode configurations, any desired prerequisite modulation axis can, however, be imprinted onto the material resulting in the possibility of balanced TE/TM polarization efficiencies. Monolithic integration of both electrode configurations within a Mach–Zehnder modulator is shown to result in an original polarization insensitive electro-optic polymer amplitude modulator for integrated optics. Design procedures including modeling, fabrication, as well as performance testing of the integrated sandwich and transverse electrode configurations device are discussed. The electrode configuration is optimized in view of ensuring both efficient poling conditions and maximal overlap of the modulation field with the active layer cross section. © 2000 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 80 (1996), S. 1773-1778 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report measurements on the isothermal relaxation dynamics of the electro-optic coefficient of electric field poled polymeric films. The studied copolymer is a side-chain Disperse Red 1/poly–methyl–metacrylate combination. The isothermal relaxation is shown to follow a Kohlrausch–Williams–Watts stretched exponential dependence, whose parameters are strongly dependent on temperature. The average decay constant is shown to follow an Arrhenius temperature dependence below the glass transition Tg, while it is described by a Vogel–Fulcher–Tamann–Hesse above Tg. The values of the decay constant confirm a much better stability of the polymer orientation with respect to guest-host systems. The relaxation is shown to be due to a broad distribution of relaxation rates, the width of which can be qualitatively described by an empirical relation, which has already been used for guest-host systems. The measurement technique permits monitoring relaxation in a standard dielectric relaxation configuration and performing unconventional poling of the samples. © 1996 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 53 (1988), S. 2251-2253 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Second-harmonic generation was observed in a 7-mm-thick 3-methyl-4-nitropyridine-1-oxide crystal at the 1.32 and 1.34 μm emission lines of a Q-switched, mode-locked Nd3+:YAG laser, emitting short pulses of duration of 160 ps. A remarkably high effective conversion rate of 50% was measured by pump depletion in a type-I phase-matched configuration.
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 55 (1989), S. 2594-2596 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The complete set of elastic and photoelastic constants of 3-methyl 4-nitropyridine 1-oxide (POM) organic single crystals is measured by Brillouin scattering. The acousto-optic figures of merit are then derived and the anisotropy of the longitudinal and transverse acoustic wave velocity clearly evidenced from the knowledge of these constants. POM appears to be a promising material for acousto-optical devices as light deflectors and modulators. It is shown that a Bragg cell using POM as an interaction medium would combine several favorable technical features.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 64 (1988), S. 3309-3311 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Huge gain values (〉107) are evidenced in parametric amplification of infrared subpicosecond pulses using two successive organic N-(4-nitrophenyl)-L-prolinol crystals acting as parametric amplifiers. Temporal analysis of parametric emission in the first crystal is performed in the second one. Application to the detection of long-wavelength pulses (〉1.6 μm) is demonstrated with a high temporal resolution.
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 66 (1995), S. 2019-2021 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Organomineral crystals are engineered to combine the favorable properties of organic and inorganic materials. High gain parametric emission and amplification at telecommunications wavelengths are demonstrated in an organomineral crystal, 2-amino-5-nitropyridinium-dihydrogen phosphate. A novel angle-noncritical type-II phase-matching configuration is observed in parametric emission, and parametric amplification is demonstrated at 1.5 μm. © 1995 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 64 (1994), S. 3655-3657 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Optical parametric oscillation in the molecular organic crystal NPP [N-(4-nitrophenyl)-L-prolinol] is reported at a pumping wavelength of 670 nm with pulse duration of 60 ns, and improved performance over the earlier demonstration at 592.7 nm pump wavelength (pulse duration 1 ns). The pumping scheme is simplified, the oscillation threshold substantially decreased by more than an order of magnitude to 0.5 MW/cm2, with the benefit of an increasingly wavelength noncritical configuration as the pump wavelength is shifted towards the infrared.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 67 (1995), S. 2765-2767 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The electro-optic properties of polymer films are measured by an original technique whereby a periodic sequence of poling and probing steps permits alternation of the application of orientation and dephasing potentials. Relaxation dynamics of the electro-optic coefficient of Red–Acid–Magly crosslinkable polymer films is studied as a function of the temperature of the samples. The time constant of the decay τ as measured at several temperatures is found to follow a Vogel–Fulcher–Tamann—Hesse dependence, for temperatures above glass transition. Poling the samples in the presence of a pulsed electric field leads to a r33 electro-optic coefficient as high as 6 pm/V. © 1995 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 67 (1995), S. 3081-3083 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The thermal sensitivity of the efficient type II angular phase matching configuration for frequency doubling in 2-amino-5-nitropyridinium-dihydrogen crystals has been measured accurately. The measured thermo-optic tuning sensitivity was found to be −0.303 mrad/ °C. A wavelength shift of the noncritical phase-matching angle resulting from the thermal effect is shown to correspond to a dλ/dT coefficient of 0.176 nm/ °C. © 1995 American Institute of Physics.
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