ISSN:
1600-5368
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The reaction of [Re2(CO)10] with benzophenone imine in dichloroethane, in the presence of Me3NO, leads to the binuclear title compound, nonacarbonyl(diphenylmethanimine-N)dirhenium(0)(Re—Re), [Re2(HN=CPh2)(CO)9]. Both Re atoms are in an octahedral environment. The HN=CPh2 ligand is attached to one of the metal atoms through the N atom, occupying an equatorial position. The equatorial carbonyl ligands of each octahedral fragment are staggered by 45°.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S1600536801003658
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