ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Reactions of Trichlorophosphazophosphorusdichloride, Cl3P=N—PCl2P2NCl5 reacts with SbF3 to give P2NCl3F2 from which P2NCl4F is obtained by chlorination. Sulfur oxidizes P2NCl5 to yield SP2NCl5, SO2 to yield SP2NCl5 and OP2NCl5. Reaction product from P2NCl5 and H2S is SPCl2(NH2) besides PCl3. P2NCl5 reacts with (n-C4H9)3P to give (n-C4H9)3P=N—PCl2. All new compounds are characterized by their n.m.r. spectra and their chemical behaviour.
Notes:
P2NCl5 reagiert mit SbF3 zu P2NCl3F2, aus dem mit Chlor P2NCl4F erhalten wird. Schwefel oxidiert P2NCl5 zu SP2NCl5, SO2 zu SP2NCl5 und OP2NCl5. Reaktionsprodukt aus P2NCl5 und H2S ist SPCl2(NH2) neben PCl3. Mit (n-C4H9)3P reagiert P2NCl5 zu (n-C4H9)3P=N—PCl2. Alle neuen Verbindungen sind durch ihre NMR-Spektren und ihr chemisches Verhalten charakterisiert.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19814740311
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