ISSN:
1434-4475
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract IO2F3, originally assumed to have a trigonal bipyramidal structure, is polymeric. Mass spectra confirm the existence of molecules with molecular weights up to three times the formula weight. Chemically, IO2F3 is a strong Lewis acid and fluorine ion acceptor, thus forming the anion IO2F4 −. With SbF5 it forms a further polymeric compound (IO2F3·SbF5) n .19F-NMR, mass, IR and Raman spectra confirm the proposed structures.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00912978
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