ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Two ruthenium(II) complexes with polypyridyl ligands, [Ru(bpy)2(AFO)](ClO4)2 · H2O (1) and [Ru(dmp)2 (AFO)](ClO4)2 · 1/2DMF · 1/2MeCN (2) (bpy = 2,2′-bipyridine; dmp = 2,9-dimethyl-1,10-phenanthroline; AFO = 4,5-diazafluoren-9-one; DMF = N,N-dimethylformamide), were synthesized and characterized by elemental analyses, i.r. and u.v.-vis. spectra. The structures of the two complexes were determined by single crystal X-ray diffraction techniques. To relieve ligand interaction, the coordination sphere is distorted so as to form specific angles (δ) between the polypyridyl ligand planes and coordination planes (N-Ru-N).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1015704715609
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