ALBERT

Description: Solar energy is a sustainable and low-cost renewable energy of enormous importance, especially at this time where non-renewable energy sources are unsustainable and costly. However, improving the thermal performance of a solar energy storage reactor poses some challenges. In this study, the location of fluid inlets and outlets in the given reactor design and its impact on the thermal performance were investigated. A P1 approximation radiation model coupled with shallow channel approximation of fluid flow was developed. By taking the frustum base as a reference, four fluid inlets along the edges of the frustum and two outlet locations at the base and side of the reactor were computed. Inlets located 4.81 cm from the base of the frustum and an outlet located at the side of the reactor were found to have a better thermal performance with a short conveyer energy flow system. It was also deduced that radiation applied at the edges of the frustum had better thermal performance than that applied at a quartz edge. Furthermore, increasing the laminar inflow rate from 0.36 (L/h) to 3.6 (L/h) increased the temperature distribution in the reactor. This study provides noteworthy insights of relevance to the power engineering industry and academia.

Description: Metal oxide materials are known for their ability to store thermochemical energy through reversible redox reactions. Metal oxides provide a new category of materials with exceptional performance in terms of thermochemical energy storage, reaction stability and oxygen-exchange and uptake capabilities. However, these characteristics are predicated on the right combination of the metal oxide candidates. In this study, metal oxide materials consisting of pure oxides, like cobalt(II) oxide, manganese(II) oxide, and iron(II, III) oxide (Fe3O4), and mixed oxides, such as (100 wt.% CoO, 100 wt.% Fe3O4, 100 wt.% CoO, 25 wt.% MnO + 75 wt.% CoO, 75 wt.% MnO + 25 wt.% CoO) and 50 wt.% MnO + 50.wt.% CoO), which was subjected to a two-cycle redox reaction, was proposed. The various mixtures of metal oxide catalysts proposed were investigated through the thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), energy dispersive X-ray (EDS), and scanning electron microscopy (SEM) analyses. The effect of argon (Ar) and oxygen (O2) at different gas flow rates (20, 30, and 50 mL/min) and temperature at thermal charging step and thermal discharging step (30–1400 °C) during the redox reaction were investigated. It was revealed that on the overall, 50 wt.% MnO + 50 wt.% CoO oxide had the most stable thermal stability and oxygen exchange to uptake ratio (0.83 and 0.99 at first and second redox reaction cycles, respectively). In addition, 30 mL/min Ar–20 mL/min O2 gas flow rate further increased the proposed (Fe,Co,Mn)Ox mixed oxide catalyst’s cyclic stability and oxygen uptake ratio. SEM revealed that the proposed (Fe,Co,Mn)Ox material had a smooth surface and consisted of polygonal-shaped structures. Thus, the proposed metallic oxide material can effectively be utilized for high-density thermochemical energy storage purposes. This study is of relevance to the power engineering industry and academia.