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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Environmental geology 27 (1996), S. 286-299 
    ISSN: 1432-0495
    Keywords: Abandoned coal mine drainage ; Stream pollution ; Water quality
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Osheepcheon Creek running through the Dogyae area is being polluted by the influx of the abandoned coal mine drainage. Generally, the more polluted water has lower pH and Eh and higher conductivity values. The concentrations of Mg, Ca, Fe, SO4, and some trace elements, such as Cd, Co, Cr, Mo, Ni, Pb, Rb, Sr, U and Zn, are tens to hundreds of times more concentrated in the abandoned coal mine drainage than in the unpolluted streamwater. However, most immobile toxic pollutants from the mine drainage are quickly removed from the streamwater by the precipitation of amorphous Fe hydroxide and sorption on the precipitated Fe hydroxide. The fast removal of the pollutants from the streamwater maintains the water quality of the creek as acceptable at most places along the stream path, except where the abandoned coal mine drainage flows in. However, the creek has the potential of deteriorating quickly if the mine drainage is allowed to be continuously combined with the streams. A function of pH, Eh, and conductivity has been developed with discriminant function analysis for the purpose of easy, fast, and inexpensive measurement of the degrees of pollution of the streams. The estimated pollution of the streams with the discriminant function are consistent with what the chemical compositions of the water samples indicate. The pollution map of the study area was constructed from the calculated scores with the discriminant function. The pollution map suggests that the pollutants mainly come from the west side of Osheepcheon Creek. Thus, the abandoned coal mine drainage from the west side has to be appropriately treated as soon as possible to prevent Osheepcheon Creek from being further polluted. Considering the topography, climate, and the amount of the mine drainage, an active treatment method is recommended.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Environmental geology 36 (1998), S. 271-276 
    ISSN: 1432-0495
    Keywords: Key words Mass balance equations ; Acid mine drainage ; Dilution factor ; Removal fractions ; Precipitation stoichiometry ; Point source
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  A few simple mass balance equations were developed to simultaneously estimate how much the pollutants from acid mine drainage (AMD) in stream water are diluted and removed during their migration. The application of the equations requires knowledge of the variations in the concentrations of the dissolved pollutants and the stoichiometry of the precipitation reaction of the pollutants when none of the pollutant shows a conservative behavior along the stream path. The calculation should be restricted to the pollutants showing much higher concentrations in the polluted main stream water than in the combining or diluting water of the same target area. The mass balance equations were applied to estimate the dilution factor and precipitation fractions of pollutants in Imgok Creek such as Fe, SO4 and Al from the AMD of Yeongdong mine. The results show that the estimation, especially for SO4 and Al, significantly depends on the kinds of the precipitates. When FeOHSO4 and AlOHSO4 are assumed to precipitate, the maximum removal fractions of SO4 and Al by precipitation are respectively 34% and 46% of the original input, which is much higher than the values estimated when SO4 is considered to be perfectly conservative. It indicates that the stoichiometry of precipitation reaction is very important in the interpretation of the pollutant dilution and migration and assessment of environmental impacts of AMD. The applicability of the mass balance equations may still need to be verified. However, examining the calculated dilution factor and precipitation fractions with the equations can provide invaluable information on not only the behavior but also unexpected input of the pollutants in the stream water polluted by AMD and other point sources.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Environmental geology 27 (1996), S. 286-299 
    ISSN: 1432-0495
    Keywords: Key words: Abandoned coal mine drainage ; Stream pollution ; Water quality
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract . Osheepcheon Creek running through the Dogyae area is being polluted by the influx of the abandoned coal mine drainage. Generally, the more polluted water has lower pH and Eh and higher conductivity values. The concentrations of Mg, Ca, Fe, SO4, and some trace elements , such as Cd, Co, Cr, Mo, Ni, Pb, Rb, Sr, U and Zn, are tens to hundreds of times more concentrated in the abandoned coal mine drainage than in the unpolluted streamwater. However, most immobile toxic pollutants from the mine drainage are quickly removed from the streamwater by the precipitation of amorphous Fe hydroxide and sorption on the precipitated Fe hydroxide. The fast removal of the pollutants from the streamwater maintains the water quality of the creek as acceptable at most places along the stream path, except where the abandoned coal mine drainage flows in. However, the creek has the potential of deteriorating quickly if the mine drainage is allowed to be continously combined with the streams. A function of pH, Eh, and conductivity has been developed with discriminant function analysis for the purpose of easy, fast, and expensive measurements of the degrees of pollution of the streams. The estimated pollution of the streams with the discriminant function are consistent with what the chemical compositions of the water samples indicate. The pollution map of the study area was constructed from the calculated scores with the discriminant function. The pollution map suggests that the pollutants mainly come from the west side of Osheepcheon Creek. Thus, the abandoned coal mine drainage from the west side has to be appropriately treated as soon as possible to prevent Osheepcheon Creek from being further polluted. Considering the topography, climate, and the amount of the mine drainage, an active treatment method is recommended.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Fish physiology and biochemistry 7 (1989), S. 177-183 
    ISSN: 1573-5168
    Keywords: gonadotropin ; pituitary ; testicular androgen formation ; ovarian estradiol formation ; sialic acid content ; isoelectric point
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Gonadotropins (GTH) were isolated from pituitary glands of grass carp and their properties investigated. Acetone-dried pituitaries were extracted with ammonium acetate-ethanol and were then passed through cation exchanger, anion exchanger, and gel filtration column. Two glycoprotein gonadotropins (DE I and DE II) were isolated of MW 56,000 and 53,000 daltons, respectively, as determined by gel filtration technique. Isoelectric points of the two GTHs also differed from each other. Sialic acid contents were 3.64% and 1.47% for DE I and DE II, respectively. Both GTH's stimulated, in a similar manner, testicular androgen and ovarian estradiol synthesisin vitro.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 276 (1998), S. 1125-1130 
    ISSN: 1435-1536
    Keywords: Key words 1H NMR spin ; spin relaxation ; micelle ; Triton X-100 ; sodium dodecyl sulfonate ; cetyl trimethyl ammonium bromide ; chain packing
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract  1H NMR spin–lattice and spin–spin relaxation of different types (cationic cetyltrimethyl ammonium bromide, anionic sodium dodecyl sulfonate and nonionic Triton X-100) of surfactants in water solution were studied. Simulation of the decay curves of proton relaxation shows that the spin lattice relaxation of all the samples exhibits exponentially, while the spin–spin relaxation for several protons on the hydrophobic chains forming the micellar core is bi-exponential. The fast relaxing component is attributed to the part of the segments of the hydrophobic chain, situated near or on the surface of the micellar core, while the slower relaxing component is attributed to the rest part staying in the interior. The latter exchanges with the former in equilibrium. Thus, a part of each certain segment of the hydrophobic chain has an opportunity to stay in the surface layer of the micellar core and spend some time on the interface experiencing hydrophilic environment. Generally, the protons on the methylene carbon of the hydrophobic chain nearest to the polar head have more chance to spend time in the hydrophilic environment. However, it seems to be dependent on the chemical structure of the surfactant molecule. Large size of the polar group of CTAB shows steric hindrance on the packing of the hydrophobic chain. Quantitative results are given. The fact, that the fraction of slow relaxing protons on the hydrophilic ethylene oxide long chain of Triton X-100 dominates over that of fast relaxing protons, and that their T 2 values are larger than those of the protons on the hydrocarbon chain in the interior of the micellar core, suggests that the ethylene oxide chain does not participate in the formation of the micellar core.
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  • 6
    ISSN: 1435-1536
    Keywords: Key words1H NMR relaxation ; Two-dimensional nuclear Overhauser enhancement spectroscopy ; Micellization ; Triton X-100 ; Sodium dodecyl sulfonate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Micellization of Triton X-100 (TX-100) and sodium dodecyl sulfonate (SDSN) in the presence of partially hydrolyzed polyacrylamide (PAAM) was studied by 1H NMR spin–spin and spin–lattice relaxation. Relaxation experiment results show that TX-100 behaves differently from SDSN in micellization in the presence of PAAM. PAAM causes a decrease in the critical micellar concentration of SDSN, while it has no influence on the critical micellar concentration of TX-100. The lack of cross peaks between protons of PAAM and those of TX-100 and SDSN in the 2D nuclear Overhauser enhancement spectroscopy (NOESY) spectra confirms self-aggregation of TX-100 and SDSN in the presence of PAAM. The identity of each of the corresponding interproton distances of TX-100 with and without the addition of PAAM further confirms the formation of normal TX-100 micelles in the presence of PAAM. Besides, the distances between protons on the hydrophilic and hydrophobic chains in TX-100 micelles, calculated from the 2D NOESY spectra, are remarkably shorter than those for an extended hydrophilic poly(oxyethylene) chain. This implies that the hydrophilic chain is curled upon micellization.
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  • 7
    Publication Date: 2008-03-14
    Print ISSN: 1550-7998
    Electronic ISSN: 1550-2368
    Topics: Physics
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  • 8
    Publication Date: 2012-05-24
    Print ISSN: 1550-7998
    Electronic ISSN: 1550-2368
    Topics: Physics
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  • 9
    Publication Date: 2013-10-28
    Print ISSN: 1550-7998
    Electronic ISSN: 1550-2368
    Topics: Physics
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  • 10
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