Publication Date:
2013-06-14
Description:
Two metal-organic frameworks, [Zn(dmtrz)(btrc) 1/3 ] n ( 1 ) and [Zn 2 (dmtrz) 2 (btec)(H 2 O) 2 ] n ( 2 ) (dmtrz = 3, 5-dimethyl-1-H-1, 2, 4-triazole, btrc = 1, 3, 5-benzenetricarboxylate, btec = 1, 2, 4, 5-benzenetetracarboxylate), were synthesized by hydrothermal reaction. The crystal structure analysis reveals that compound 1 is a dense 3D framework with Schläfli symbols of {4 3 } 2 {4 6 · 6 6 · 8 3 } 3 , which is a loh1 structure. Compound 2 is a 2D network. In addition, the photoluminescence of two compounds were studied in solid state at room temperature, together with their thermal analysis.
Print ISSN:
0044-2313
Electronic ISSN:
1521-3749
Topics:
Chemistry and Pharmacology
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