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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 65 (1994), S. 265-266 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: We present a novel pulsed valve design that is especially suited for use with severely corrosive gases. The design is unique in that the stem seals the gas inlet, rather than the outlet. All parts in contact with the high-pressure gas flow are constructed of ceramic and fluoroplastics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Water Resources Association 34 (1998), S. 0 
    ISSN: 1752-1688
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Architecture, Civil Engineering, Surveying , Geography
    Notes: : A continuous simulation approach is proposed for estimating water temperature exceedance probabilities using thermo-hydrodynamic modeling. The approach uses (1) a deterministic unsteady flow and heat transport model, (2) continuous hydrological and meteorological data for a long historical period, and (3) synthetic records of tributary water temperatures and other model inputs. Representative historical records of streamflow, air temperatures, and other hydrometeorological variables are obtained from nearby gages. Stochastic modeling methods are used to construct synthetic records for other model inputs, including inflow water temperatures. An application of this deterministic-stochastic approach is presented for a complex waterway in northeastern Illinois with heat discharges from several power plants and wastewater treatment plants. Statistical results from the continuous simulations are compared to results obtained from traditional event simulations. The application illustrates the information that engineers and biologists can obtain for (1) evaluating compliance with water temperature standards, and (2) assessing the effect of water temperatures on aquatic habitat.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 104 (1996), S. 8279-8291 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A study to observe higher vibrational levels in NCO(A˜ 2Σ+) and the onset of predissociation in this molecule has been carried out. Laser fluorescence spectra have been recorded over the wave number range 27 300–32 900 cm−1, from the A˜(0,0,2)–X˜(0,0,0) band up through the B˜(1,0,0)–X˜(0,0,0) band. Vibrational assignments have been made for a number of newly observed A˜–X˜ bands, and band origin wave numbers and upper level rotational constants have been derived from comparison of experimental spectra with simulations. Decay lifetimes for excitation of a large number of both assigned and unassigned excited vibronic levels have been determined. The onset of predissociation appears to occur at energies slightly below that of the B˜(0,0,0) level. © 1996 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 103 (1995), S. 6479-6489 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The reaction of CN with O2 has been studied through a photolysis-probe laser experiment in a cell at a total pressure of 70 mTorr. Rotationally hot CN reagent was prepared by 193 nm photolysis of BrCN. NCO(X˜ 2Π) product in various vibronic levels was detected by laser fluorescence excitation in its A˜ 2Σ+–X˜ 2Π band system at variable delays after the photolysis laser. In order to monitor the CN collisional relaxation which is taking place simultaneously with the reaction, we have also derived the CN rotational state distribution as a function of the photolysis-probe delay from laser fluorescence excitation spectra of the CN B 2Σ+–X 2Σ+ (0,0) band. From these observations, we deduce that rotationally hot CN reacts more slowly than thermalized CN. Moreover, reaction of the former yields NCO product with greater bending vibronic excitation. These results are compared with previous dynamical studies of this reaction, carried out with crossed beams and in cells. © 1995 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 101 (1994), S. 238-245 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The spectroscopy of hydrogen iodide Rydberg states is investigated by resonantly enhanced multiphoton ionization (REMPI), utilizing time-of-flight mass spectrometry for detection. A (2+1) REMPI excitation mechanism provides access to electronic states in the region 64 641–71 352 cm−1. Two-photon selection rules allow the observation of transitions forbidden in the HI absorption experiments. Many of the assigned Rydberg states contain underlying, unassigned structure with anomalous intensity fluctuations and apparent breaking off of branches. Additionally, we observe autoionized levels, most likely accessed by either a (3+1) or a direct four-photon excitation. Molecular constants are calculated for all HI bands observed. Also included is the first REMPI study of iodine atoms coming from photolyzed HI precursor.
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 107 (1997), S. 680-690 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The fluorescence excitation spectrum of the Ar–HCO van der Waals complex in the vicinity of the B˜ 2A′–X˜ 2A′ 000 band of free HCO is reported. At least eight bands associated with the complex have been detected. From the spectral shift of the lowest energy Ar–HCO band from the origin of the free HCO transition, we estimate the Ar–HCO binding energy in the excited electronic state to be at least 13 cm−1 greater than that in the ground state. Rotational analysis of some of the bands has been carried out, and average Ar–HCO separations (∼3.7 Å) in both electronic states determined. Several of the bands were assigned as hot bands from the first excited bend–stretch level (K″=1) in the ground electronic state. From the derived A rotational constants, we conclude that the ArCO framework has an approximately T-shaped geometry in both electronic states. The decay lifetime of the upper state of the strongest Ar–HCO band was measured and was found to be somewhat smaller than those previously measured for low rotational levels of free HCO. With the high signal-to-noise ratio in this study, it was also possible to observe transitions in the free H13CO isotopomer. A rotational analysis of the B˜ 2A′–X˜ 2A′ 000 band of the H13CO isotopomer was carried out. The isotopic shifts of the origins of the 301 and 201 bands were also measured, and a normal mode analysis of HCO(B˜) was carried out. © 1997 American Institute of Physics.
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 107 (1997), S. 9755-9758 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The laser fluorescence excitation spectrum of the origin band of an electronic transition in the CH2CFO radical was recorded with partial rotational resolution using a supersonic, rotationally cold beam. The radical was prepared in a pulsed free jet by 193 nm photolysis of acetyl fluoride diluted in helium or argon. The rotational structure of the band is consistent with an in-plane electronic transition of this near oblate rotor. In analogy with the vinoxy radical, this transition is designated as B˜2A′′−X˜2A′′. Spectroscopic constants were derived from a fit to the assigned rotational transitions. The lower state rotational constants agree with those calculated from an ab initio CH2CFO equilibrium structure [M. Furubayashi, I. Bridier, S. Inomata, N. Washida, and K. Yamashita, J. Chem. Phys. 106, 6302 (1997)]. The present study thus provides confirmation of the assignment of the molecular carrier as CH2CFO and eliminates the alternative assignment to FCO [B. A. Williams and J. W. Fleming, J. Chem. Phys. 106, 4376 (1997)]. © 1997 American Institute of Physics.
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  • 8
    Publication Date: 1996-06-01
    Print ISSN: 0021-9606
    Electronic ISSN: 1089-7690
    Topics: Chemistry and Pharmacology , Physics
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  • 9
    Publication Date: 2009-09-14
    Print ISSN: 0003-6951
    Electronic ISSN: 1077-3118
    Topics: Physics
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  • 10
    Publication Date: 2018
    Description: A suite of near‐surface geophysical methods was deployed at kilometer scales to characterize fracturing zones across the Rio Icacos Watershed in the Luquillo Mountains (Puerto Rico). Results were combined with stress models calculated for the topographic variability across the knickzone and showed an increase in fracturing width with proximity to the knickpoint that is indicative of a release in compressive stress near the knickpoint. Abstract The Rio Icacos watershed in the Luquillo Mountains (Puerto Rico) is unique due to its extremely rapid weathering rates. The watershed is incised into a quartz diorite that has developed a large knickzone defining the river profile. Regolith thickness within the watershed generally decreases from 20 to 30 m at the ridges to several meters in the quartz diorite‐dominated valley to tens of centimeters near the major river knickpoint, as determined from previous studies. Above the knickzone, we observe spheroidal corestones, but below this weathering is much less apparent. Measured erosion rates from previous studies are also high in the knickzone compared with upper elevations within the river profile. A suite of near‐surface geophysical methods (i.e. ground penetrating radar and terrain conductivity) capable of fast data acquisition in rugged landscapes, was deployed at kilometer scales to characterize critical zone structure. Concentrations of chaotic ground penetrating radar (GPR) reflections and diffraction hyperbolas with low electrical conductivity were observed in vertical zones that outcrop at the land surface as areas of intense fracturing and spheroidally weathered corestones. The width of these fractured and weathered zones showed an increase with proximity to the knickpoint, and was attributed to dilation of these sub‐vertical fractures near the knickpoint, as postulated theoretically by a stress model calculated for the topographic variability across the knickzone in the Rio Icacos, and that shows a release of compressive stress near the knickpoint. We hypothesize that erosion rates increase in the knickzone because of this inferred dilation of fractures. Specifically, opened fractures could enhance access of water and in turn promote spalling, erosion, and spheroidal weathering. This study shows that ground‐based hydrogeophysical methods used at the landscape‐scale (traditionally applied at smaller scales) can be used to explore critical zone architecture at the scales needed to explain the extreme variability in erosion rates across river profiles. © 2018 John Wiley & Sons, Ltd.
    Print ISSN: 0360-1269
    Electronic ISSN: 1096-9837
    Topics: Geography , Geosciences
    Published by Wiley
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