ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Studies on the Autoxidation of 1-Phenylbuta-1,3-diene and 2-Phenylbuta-1,3-dieneHydrogenation of the polymeric peroxides formed during the autoxidation of 1-phenylbuta-1,3-diene (1) and 2-phenylbuta-1,3-diene (10) at 50°C in an autoclave yielded 1-phenylbutane-3,4-diol (5) and 2-phenylbutane-1,4-diol (12), respectively.The LiAlH4 reduction of 1-phenylbuta-1,3-diene oxidate (50°C) yielded cinnamyl alcohols (4) as a major product.The oxygen-containing polymeric products formed along with Diels-Alder dimers during the oxidation of the title substances at 140°C showed no degradation after subjecting to hydrogenation and are therefore considered as polyethers.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19863280105
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