ISSN:
0947-3440
Keywords:
Nagilactones
;
Diels-Alder reactions
;
Allylic compounds
;
Rearrangements
;
Cycloadditions
;
Lactones
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A very short and straightforward synthesis towards highly functionalized dienes is described. The homochiral starting material, unsaturated β-oxo ester 2, can be prepared by enzyme-catalyzed saponification. The utility of the dienes has been demonstrated in a cycloaddition with N-phenyltriazolidinone as the dienophile. The Diels-Alder reaction is highly diastereoselective, yielding only one diastereomer.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.199719970214
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