ISSN:
1600-5368
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The title compound, RhCp*Me(Cl)(PMe3) or [RhCl(CH3)(C10H15)(C3H9P)], where Cp* is pentamethylcyclopentadienyl, has a pseudo-tetrahedral coordination geometry. The Cp* ligand is planar and η5-coordinated. The molecular structure can be described as a so-called three-legged piano-stool. The rhodium–methyl, rhodium–chlorine and rhodium–phosphorus distances are 2.255 (4), 2.3764 (18) and 2.2436 (13) Å, respectively.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S1600536801016798
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