ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The partial cross sections and angular distribution parameters, β, have been determined for the 2p subshell in SiCl4. These data were obtained with angle-resolved photoelectron spectroscopy and the use of synchrotron radiation for a range of photon energies from 114 to 150 eV. The same quantities were calculated by use of a multiple scattering Xα method, and the agreement between experiment and theory is very good. In particular, the behavior of shape resonances was well predicted. The nature of shape resonances as a function of molecular orbitals in SiCl4 is discussed, and the importance of such intercomparison is emphasized.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.450186
Permalink