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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Sedimentology 38 (1991), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Carbonate cements in late Dinantian (Asbian and Brigantian) limestones of the Derbyshire carbonate platform record a diagenetic history starting with early vadose meteoric cementation and finishing with burial and localized mineral and oil emplacement. The sequence is documented using cement petrography, cathodoluminescence, trace element geochemistry and C and O isotopes.The earliest cements (Pre-Zone 1) are locally developed non-luminescent brown sparry calcite below intrastratal palaeokarsts and calcretes. They contain negligible Fe, Mn and Sr but up to 1000 ppm Mg. Their isotopic compositions centre around δ18O =−8.5‰, δ13C=−5.0‰. Calcretes contain less 13C. Subsequent cements are widespread as inclusion-free, low-Mg, low-Fe crinoid overgrowths and are described as having a‘dead-bright-dull’cathodoluminescence. The‘dead’cements (Zone 1) are mostly non-luminescent but contain dissolution hiatuses overlain by finely detailed bright subzones that correlate over several kilometres. Across‘dead'/bright subzones there is a clear trend in Mg (500–900 ppm), Mn (100–450 ppm) and Fe (80-230 ppm). Zone 1 cements have isotopic compositions centred around δ18O =−8.0‰ and δ13C=−2.5‰. Zone 2 cement is bright, thin and complexly subzoned. It is geochemically similar to bright subzones of Zone 1 cements. Dull Zone 3 cement pre-dates pressure dissolution and fills 70% or more of the pore space. It generally contains little Mn, Fe and Sr but can have more than 1000 ppm Mg, increasing stratigraphically upwards. The δ18O compositions range from −5.5 to −15‰ and the δ13C range is −1 to + 3.20/00. Zone 4 fills veins and stylolite seams in addition to pores. It is synchronous with Pb, Ba, F ore mineralization and oil migration. Zone 4 is ferroan with around 500 ppm Fe, up to 2500 ppm Mg and up to 1500 ppm Mn. Isotopic compositions range widely; δ15O =−2.7 to −9‰ and δ13C=−3.8 to+2.50‰.Unaltered marine brachiopods suggest a Dinantian seawater composition around δ15O = 0‰ (SMOW), but vital isotopic effects probably mask the original δ13C (PDB) value. Pre-Zone 1 calcites are meteoric vadose cements with light soil-derived δ13C and light meteoric δ18O. An unusually fractionated‘pluvial’δ15O(SMOW) value of around — 6‰ is indicated for local Dinantian meteoric water. Calcrete δ18O values are heavier through evaporation. Zone 1 textures and geochemistry indicate a meteoric phreatic environment. Fe and Mn trends in the bright subzones indicate stagnation, and precipitation occurred in increments from widespread cyclically developed shallow meteoric water bodies. Meteoric alteration of the rock body was pervasive by the end of Zone 1 with a general resetting of isotopic values. Zone 3 is volumetrically important and external sources of water and carbonate are required. Emplacement was during the Namurian-early Westphalian by meteoric water sourced at a karst landscape on the uplifted eastern edge of the Derbyshire-East Midland shelf. The light δ18O values mainly reflect burial temperatures and an unusually high local heat flow, but an input of highly fractionated hinterland-derived meteoric water at the unconformity is also likely. Relatively heavy δ13C values reflect the less-altered state of the source carbonate and aquifer.Zone 4 is partly vein fed and spans burial down to 2000 m and the onset of tectonism. Light organic-matter-derived δ13C and heavy δ18O values suggest basin-derived formation water. Combined with textural evidence of geopressures, this relates to local high-temperature ore mineralization and oil migration. Low water-to-rock ratios with host-rock buffering probably affected the final isotopic compositions of Zone 4, masking extremes both of temperature and organic-matter-derived CO2.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Sedimentology 32 (1985), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: A laterally extensive calcrete profile has been identified in the Late Asbian (Lower Carboniferous) shallow marine shelf limestones of the Llangollen area, North Wales. The upper surface of the profile is defined by a laterally discontinuous palaeokarstic surface and by laminated calcareous crusts which developed within the underlying limestone.The profile contains a unique series of early pore-filling vadose cements which only occur down to 1 m below the palaeokarstic surface. Cathodoluminescence reveals that these cements pre-date the late pore-filling meteoric phreatic cements which occur throughout local Asbian lithologies. A spar cement stratigraphy has been established for the calcrete profile. Subaerial vadose cements comprise two generations of non-luminescent cement, followed by a brightly luminescent generation which occasionally shows an acicular habit. This needle-fibre calcite represents the final stage of vadose cementation. Precipitation of vadose cements was contemporary with subaerial alteration and micritization of the limestone.Textures, visible only with cathodoluminescence, provide evidence of recurrent periods of fabric dissolution. The most extensive phase of dissolution occurred immediately after the precipitation of the non-luminescent subaerial vadose cements. Several different textures have been recorded, each reflecting the morphology of a partially dissolved substrate. Dissolution textures are generally confined to the walls of the larger pores and to early brecciation fractures. These probably acted as fluid pathways in the calcrete during early subaerial diagenesis.Much of the non-marine micrite in the calcrete profile appears as needle-fibre calcite under cathodoluminescence. This acicular calcite was probably formed in response to localized supersaturation of meteoric pore fluids caused by periods of near-surface evaporation. Since needle-fibre luminescence is strongly variable, these ambient conditions are not believed to have directly controlled the activator ion concentrations of cementing pore waters. Needle-fibre calcite is considered to be a cement precipitate which has almost completely recrystallized to micrite, probably during the late stages of subaerial diagenesis. Two generations of subaerial micrite which define a ‘micrite stratigraphy’, have been distinguished under cathodoluminescence.Reconstructing the diagenetic history of this ancient calcrete profile has revealed that subaerial alteration was multistaged, with many diagenetic processes acting simultaneously during a single phase of emergence.
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  • 3
    Publication Date: 2002-01-01
    Description: The southern Arabian (Persian) Gulf is at present the site of extensive carbonate sedimentation, as was the case during Pleistocene interglacial marine highstands. During glacial lowstands the basin was subaerially exposed, and aeolian sedimentation predominated. Most of the southern Arabian Gulf floor is underlain by Quaternary carbonates, and scattered outcrops may be found onshore. These belong to three formations: the aeolian Ghayathi Formation, the continental Aradah Formation and the marine Fuwayrit Formation. The Fuwayrit Formation consists of three members, separated by subaerial exposure surfaces. These are, from the base upwards, the shallow marine Futaisi and Dabb'iya Members, and the aeolian Al Wusayl Member. Offshore, at least six Quaternary sequences are present within the uppermost 50 m of sediment. No reliable direct age dates have been acquired from Pleistocene shallow marine or coastal deposits in the southern Arabian Gulf. It has therefore been necessary to infer the ages of these sediments by a comparison of their stratigraphy and elevation with deposits known from other parts of the world. We regard this approach as valid because the southern Gulf coastline lacks evidence for significant widespread neotectonic uplift, and halotectonic effects are localized. This comparison indicates that the Fuwayrit Formation was deposited during the last interglacial (oxygen isotope substage 5e), as (1) these sediments represent the youngest pre-Holocene marine deposits, and (2) they are found at an elevation correlative with many substage 5e deposits from other parts of the globe. Sedimentary evidence reveals two highstands during this period, peaking at around 1.5 m and 6 m above present sea level, respectively. Offshore sediments indicate that sea level did not fall as far as 24 m below present level in the intervening regression. Following the second highstand, sea level fell to more than 23 m below present level, before briefly rising once again (late isotope stage 5). This later highstand probably peaked between 17 and 7 m below present level. The sequence underlying the Fuwayrit Formation was probably deposited during the penultimate interglacial (late oxygen isotope stage 7). It is also likely that the Ghayathi Formation aeolianites were largely sourced from this sequence. Facies analysis of offshore core sediments indicates that sea level reached at least 15 m below present level during this period. Widespread evidence exists for a Holocene sea level higher than at present in the southern Arabian Gulf, indicating that it peaked at 1-2 m above present level, c. 5.5 ka bp. Pleistocene deposits preserved in the southern Arabian Gulf provide a record of changing palaeowinds and palaeoclimates. Currently, the region experiences a hyper-arid to arid climate, with facies patterns dominated by the northwesterly shamal wind. The Ghayathi Formation was originally deposited under an arid climatic regime, which allowed the sediments to remain unconsolidated. The dunefield was later remodelled under conditions of increasing wind speed, with a change in wind direction from NNW to WNW. These changes are thought to reflect the onset of glaciation. Palaeocurrent directions from the Al Wusayl Member, combined with sedimentary evidence from the Futaisi and Dabb'iya Members, indicate that during the peak of the last interglacial the prevailing wind (the palaeo-shamal') blew from the NE. Compelling evidence for a pluvial episode during this period is provided by abundant and widespread dissolution (palaeokarstic) pits found in the top surface of the Futaisi Member, believed to represent the former positions of abundant trees or large plants.
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  • 4
    Publication Date: 1985-12-01
    Print ISSN: 0037-0746
    Electronic ISSN: 1365-3091
    Topics: Geosciences
    Published by Wiley
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  • 5
    Publication Date: 1991-08-01
    Print ISSN: 0037-0746
    Electronic ISSN: 1365-3091
    Topics: Geosciences
    Published by Wiley
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  • 6
    Publication Date: 1993-01-01
    Description: The East Kirkton Limestone is typically a carbonate/organic laminite characterised at many levels by abundant radial-fibrous calcite (RFC) spherules and by less common larger stromatolite-like accretions of laminated botryoidal RFC. The spherules are mostly c. 1 mm in diameter and have cyanophyte and chlorophyte inclusions. Some spherules enclose parallel bundles of complete cyanophyte fibres and probably grew within a living cyanophyte mat. The botryoidal accretions were commonly seeded upon wood and other exposed organic remains such as bone, and they completely enclose twigs and branches where these were held above the sediment surface. Botryoidal accretions commonly contain the remains of a benthos of cyanophytes, chlorophytes and ostracods.Both types of calcite have carbon and oxygen stable isotope values similar to those of known fresh-water precipitates. Their stable isotope and trace element geochemistries are consistent with precipitation on the floor of a tropical fresh-water lake within a volcanic setting, but removed from the influence of any hot-spring activity. Spherules and botroids are mineralogically closely similar and, whilst precipitation may have been biogenically mediated, they are regarded as passive lake floor cements.The carbonate laminae are dominated by rhombohedral calcite. Many of these laminae may have originated as calcite suspensoids which settled to the lake floor during relatively brief precipitation events, blanketing the normally richly organic substrate, smothering the cyanophyte mats, and leading to the preservation of individual organic laminae. Crystals later became enlarged and intergrown within the sediment, but this occurred early and prior to significant compaction, because detail of fragile and degradable organic constituents is commonly preserved. The likely source of the carbonate is through leaching of the local basic volcanic terrain. The precipitation of two types of calcite implies regular fluctuations in the chemistry of the lake waters, or in the factors controlling precipitation, which may have been a biogenic and/or seasonal effect.
    Print ISSN: 1755-6910
    Electronic ISSN: 1755-6929
    Topics: Geosciences
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  • 7
    Publication Date: 2002-01-01
    Print ISSN: 0305-8719
    Electronic ISSN: 2041-4927
    Topics: Geosciences
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  • 8
    Publication Date: 2016-07-01
    Print ISSN: 0266-6979
    Electronic ISSN: 1365-2451
    Topics: Geosciences
    Published by Wiley
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  • 9
    Publication Date: 2017-03-01
    Print ISSN: 0266-6979
    Electronic ISSN: 1365-2451
    Topics: Geosciences
    Published by Wiley
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  • 10
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