ISSN:
1573-9171
Keywords:
homolytic addition
;
benzyl bromide
;
unsaturated compounds
;
iron pentacarbonyl
;
DMF
;
HMPA
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Radical addition of benzyl bromide to unsaturated compounds containing substituents of a different polar nature, CH2=CHX (X=C4H9, SiMe3, CF3, CO2Me, CN, H), was conducted in the presence of the Fe(CO)5 + DMF (HMPA) system. Adducts were obtained and their structure was demonstrated by13C NMR and mass spectrometry.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00863820
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