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Electronic Structure of Indandiones (1987)

Tyutyulkov, N. ; Tasseva, M. ; Georgiev, E.

New York, NY : Wiley-Blackwell

Journal für Praktische Chemie/Chemiker-Zeitung 329 (1987), S. 780-786

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ISSN: 0021-8383

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: It is shown that the anions of the enolate forms of 1, 2- and 1, 3-indandiones have antiaromatic character. This conclusion is reached after studying the geometry, the electron density distribution and the energy spectrum of the molecules.The anion of the 1,2-indandione enolate form is unstable because of strong electron-vibronic interaction.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/prac.19873290505

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