ALBERT

Notes: Development of a diagenetic anhydrite bed at the base of the Cretaceous Maha Sarakham Saline Formation (the `Basal Anhydrite' member) of the Khorat Plateau in north-eastern Thailand took place due to leaching and/or pressure dissolution of salt at the contact between an underlying active sandstone aquifer system and an overlying massive halite-dominated evaporite sequence. Basal evaporites composed of halite with intercalated anhydrite of the latter sequence are undergoing dissolution as a result of subsurface flushing, with anhydrite produced as the insoluble residue. The result is a 1·1 m thick interval of nodular anhydrite displaying unique, basin-wide continuity. Observed textures, petrographic features and chemical data from the anhydrite and associated authigenic minerals support the origin of the Basal Anhydrite Member as an accumulation residue from the dissolution of the Maha Sarakham salts. Petrographically, the anhydrite in this unit is made up of crystals that are blocky and recrystallized, sheared, generally elongated and broken, and is bounded at the bottom by organic-rich stylolite surfaces. Authigenic and euhedral dolomite and calcite crystals are associated with the anhydrite. Traces of pyrite, galena and chalcopyrite are present along the stylolite surfaces suggesting supply of fresh water from the underlying sandstone at highly reducing conditions of burial. The δ34S of sulphate in the Basal Anhydrite averages 15 ‰ (CDT) and falls within the isotopic composition of the anhydrite in the Cretaceous Maha Sarakham Formation proper and the Cretaceous values of marine evaporites. Measured δ18O in dolomite range from −4·37 to −14·26‰ (PDB) suggesting a re-equilibration of dolomite with basinal water depleted in 18O and possible recrystallization of dolomite under relatively elevated temperatures. The δ13C, however, varies from +1·57 to −2·53‰ (PDB) suggesting a contribution of carbon from oxidation of organic matter. This basal anhydrite bed, similar to basinwide beds found at the bottom of many giant evaporite sequences, has always been considered to be depositional. Here, at the base of the Maha Sarakham Formation, we demonstrate that the anhydrite is diagenetic in origin and was formed by accumulation of original anhydrite by dissolution of interbedded halite from waters circulating though the underlying aquifer: it represents an `upside-down' caprock.

Notes: The depositional settings for primary and early diagenetic evaporite deposits generally fall into three categories: marginal (mixed shallow-subaqueous and subaerial), shallow and deep subaqueous. These three environmental groupings hold for both marine and nonmarine settings, although the details of continental evaporites may be far more complex than in most marine-fed water bodies. The primary evaporite morphologies from many continental (playa), hypersaline marine and marine-marginal depositional settings are reasonably well understood, because of the numerous detailed studies of recent, Holocene and Cenozoic deposits that serve as models for sedimentary interpretation. The sedimentological features that develop in deeper water settings are inferred, based on examination of unaltered Cenozoic deposits. Each environmental setting develops characteristic depositional features and patterns, and one facies grades into the next. Because there may be significant physiochemical changes in water composition during deposition as well as sudden change(s) in both water depth and basinal circulation, description and interpretation of evaporative rocks should not be based on mineralogy alone, but on the distinct sedimentary characteristics of each part of a deposit. In cases where sediments still reflect their primary mineralogy and morphology, most of the environments can now be recognized; however, geochemical studies are commonly required to determine the source(s) of the original water. The determinative geochemical techniques that presently serve as a support to sedimentologic study include studies of fluid inclusions, bromine content of chloride salts, and the stable isotopes of strontium, sulphur, carbon and oxygen. Only after these and perhaps other chemical analyses are considered can the full depositional history of a region be reasonably unravelled.