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  • 1
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 262 (1976), S. 572-573 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] It is generally accepted that in cavitation erosion the main damage results from the collapse of single cavitation bubbles near the solid surface. In such a collapse an inward moving microjet is always formed against the solid surface4 and the damaging effect of the microjet with velocity as high ...
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  • 2
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 250 (1974), S. 408-410 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The branched PAM sample was synthesised by grafting PAM chains on to a small, nucleus molecule. The nucleus was prepared by reacting tetraethylene pentamine with epichlorohydrin. A typical structure of this backbone molecule may be represented as follows: HOR HOR N CH2CH2 N ROH CH2CH2 N ROH CH2CH2 ...
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 15 (1980), S. 2097-2102 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The dynamic mechanical properties of a series of phthalocyanine polymers with varying aliphatic chain length linking stable phthalocyanine nuclei have been studied. Dynamic shear modulus and polymer loss factor were determined using a torsion pendulum. Polymer fracture energies were also determined using both the standard compact tension specimens and double-tapered cantilever beam specimens. The results showed that both the dynamic shear modulus and the glass transition temperature increased with decreasing molecular flexibility and increasing extent of cure. The fracture energies increased with increasing molecular flexibility. It was also shown that extended thermal treatment could greatly embrittle the thermosetting polymers and hence reduce the fracture toughness, even though such treatments usually promoted crosslinking leading to higher moduli and glass transition temperatures for these polymers.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 16 (1981), S. 2657-2664 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The fracture energies of elastomer-modified epoxy polymers have been determined over a range of strain rates from 10−2 to 103 sec−1. The modifiers included a liquid carboxyterminated butadiene acrylonitrile and a solid rubber. They were used alone and also in combination. In all cases, the modifiers increased the toughness of the base resin by orders of magnitude and one combination of liquid and solid rubber increased toughness by 60 times. There was a general decrease in fracture energy with increasing strain rate but even during impact testing the modified epoxys were 10 to 20 times tougher than the base polymer. Scanning electron microscopy revealed that, when combined with the liquid rubber, the solid rubber induced a localized shear yielding.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 16 (1981), S. 2657-2664 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The fracture energies of elastomer-modified epoxy polymers have been determined over a range of strain rates from 10−2 to 103 sec−1. The modifiers included a liquid carboxyterminated butadiene acrylonitrile and a solid rubber. They were used alone and also in combination. In all cases, the modifiers increased the toughness of the base resin by orders of magnitude and one combination of liquid and solid rubber increased toughness by 60 times. There was a general decrease in fracture energy with increasing strain rate but even during impact testing the modified epoxys were 10 to 20 times tougher than the base polymer. Scanning electron microscopy revealed that, when combined with the liquid rubber, the solid rubber induced a localized shear yielding.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 21 (1977), S. 1825-1833 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The elongational flow behavior of dilute polymer solutions is of great current interest because it has been suggested that elongational viscosity effects may be involved in a number of phenomena such as turbulent drag reduction and flow cavitation suppression. Unfortunately, recent experiments, in trying to investigate elongational effects, have produced widely varying results. In this paper, an attempt is made to analyze one of the factors that contribute to this diversity. By using a generalized convected Maxwell model, it is shown that in a transient elongational flow, both stretching rate and flow time must reach the proper values before high stress levels can be observed. This is true for both accelerating flows such as through a cone or wedge and decelerating flows such as in a free jet. Since most previous experiments have not considered flow time, consistent results cannot be expected. Consequently, the proper control of all flow conditions is an essential requirement when trying to observe high stress levels. The results presented here provide valuable guidelines in this regard.
    Additional Material: 2 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 26 (1988), S. 55-64 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Copolymers of vinylidene fluoride and trifluroethylene are presently being considered for many piezoelectric applications. In contrast to the poly(vinylidene fluoride) homopolymer, a transition from the room temperature ferroelectric phase to a paraelectric phase has been observed in these copolymers. The temperature of this transition was determined by measuring the position of the endothermic peak observed in the differential scanning calorimeter. The rate of cooling from the paraelectric to ferroelectric phase was found to affect the temperature at which the transition occurred on subsequent heating. Changing the conditions under which molten polymer initially crystallized into the paraelectric phase had an even greater effect on the resultant transition temperature. In addition to the DSC studies, wide-angle x-ray measurements were performed on samples subjected to different thermal treatments. No significant differences were found in the x-ray scans of these copolymers.
    Additional Material: 7 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 441-448 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thermomechanical analysis was carried out for various phthalocyanine resins. The polymer based on the C-10 diamide resin was then chosen for evaluation as a potential composite matrix material. Prepregs with Thornel 300 graphite reinforcements were successfully prepared using a hot-melt technique. The processability of this material was studied by employing instrumental techniques including differential scanning calorimetry, thermal gravimetric analysis and dynamic dielectric analysis. A cure cycle was developed for the fabrication of angle-ply laminate using the conventional vacuum-bag technique in a hydraulic press. Laminate mechanical properties both in tension and in flexure were determined. The results for the C-10/T-300 samples were shown to be similar to those of an epoxy/graphite and a polyimide/graphite composite system.
    Additional Material: 13 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 28 (1990), S. 1187-1205 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The dynamic bulk modulus of elasticity has been measured for 14 different rubbery elastomers: three natural rubbers, five neoprenes, three polyurethanes, and one each of butyl, nitrile, and butadiene types. The measurements ranged in temperature from -10 to +40°C, at frequencies from 5 to 3000 Hz, but mostly in the range 100-1000 Hz, at 2.5 MPa pressure. Values of the real (storage) part of the modulus fell within 35% of the mean value of 2.9 GPa for all elastomers, whereas loss moduli were a few percent of the storage moduli. Master curves were obtained for two neoprenes, a polyurethane, and a butyl rubber. These were fitted by hyperbolic functions with four adjustable parameters. Effects of room-temperature aging in artificial sea water were also studied. Aging versus time profiles fell into two distinct forms. Natural rubbers were least stable, neoprenes were intermediate, and urethanes proved most stable in bulk modulus.
    Additional Material: 6 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 16 (1972), S. 3169-3184 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Two possible drag reduction mechanisms were examined by studying the viscoelastic effects of polymer solutions for the separate cases of oscillatory shear flow and elongational flow. The constitutive equation used was based on a modified dumbbell molecular model which predicts non-Newtonian viscosity and both the primary and the secondary normal stress differences. It can be shown that when this constitutive equation is arranged in the form of the Oldroyd model, the latter becomes a special case of this more general equation. The present results show that viscoelastic effects on the mean local rate of energy dissipation of a fluid element in an oscillatory motion are negligibly small. However, such effects introduce very large increases in the elongational viscosity as the stretching rate exceeds a certain limiting value and the flow time exceeds the terminal relaxation time of the fluid. The relative merits of these findings as possible explanations of turbulent drag reduction are briefly discussed.
    Additional Material: 7 Ill.
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