ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions Under mild conditions α-polynitroalkyl sulfones with the general formula RSO2C(NO2)2R′ are split at the C-SO2 bond under the action of both nucleophilic (alcohols, water, and bases) and electrophilic (the halogens, SO)2Cl2, BrONO2, and HC1) reagents to form the corresponding polynitroalkane and sulfonic acid derivatives. The attack of the nucleophiles is directed at the sulfur atom, and that of the electrophiles is directed at the α-carbon atom bonded to the nitro groups.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00921846
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