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  • 1
    Electronic Resource
    Electronic Resource
    Studies of Ligand Transfer between Metal Halides and Free Radicals from Peroxides1 (1965)
    s.l. : American Chemical Society
    Journal of the American Chemical Society 87 (1965), S. 1508-1514 
    Details
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/ja01085a018
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  • 2
    Electronic Resource
    Electronic Resource
    Kinetic Determination of the Monomer-Dimer Equilibrium for Cupric Acetate in Acetic Acid Solutions (1965)
    s.l. : American Chemical Society
    Inorganic chemistry 4 (1965), S. 1527-1533 
    Details
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/ic50033a001
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  • 3
    Electronic Resource
    Electronic Resource
    Kinetics of Electron-Transfer Oxidation of Alkyl Radicals by Copper(II) Complexes (1965)
    s.l. : American Chemical Society
    Journal of the American Chemical Society 87 (1965), S. 4855-4866 
    Details
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/ja00949a033
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  • 4
    Electronic Resource
    Electronic Resource
    Biologically Active Organotin Polymers (1985)
    Oxford, UK : Blackwell Publishing Ltd
    Annals of the New York Academy of Sciences 446 (1985), S. 0 
    Details
    ISSN: 1749-6632
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Natural Sciences in General
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1749-6632.1985.tb18396.x
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  • 5
    Electronic Resource
    Electronic Resource
    A bimodal lognormal model of the distribution of strength of carbon fibres: effects of electrodeposition of titanium di (dioctyl pyrophosphate) oxyacetate (1986)
    Springer
    Journal of materials science 21 (1986), S. 3912-3920 
    Details
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The tensile strength distribution of Fortafil-3 carbon fibres of circular cross-section has been investigated at different gauge lengths. The unimodal Weibull, unimodal lognormal and bimodal lognormal models were tested. Estimating the model parameters by the method of maximum likelihood, and testing each model by the Kolmogorov-Smirnov goodness-of-fit statistic at prescribed levels of significance, it is found that the data for untreated unsized fibres fit a bimodal lognormal model best. The proportions of the low and high strength populations,p andq, respectively, did not show any well-defined trend with gauge length and had average values close to 0.5. But the lognormal mean for each population showed an increasing trend with decreasing gauge length. It is inferred thatp andq are, respectively, related to the presence of surface flaws and internal defects, both of which probably have the same structural origin. After electrodeposition of titanium di (dioctyl pyrophosphate) oxyacetate (TDPO), the fibre strength was still best approximated by a bimodal lognormal distribution. But the weighting factorp for the weak population was reduced markedly, with a corresponding increase ofq, indicating the healing of surface flaws during electrodeposition of a protective layer of TDPO. Furthermore, in contrast to the observations with untreated fibres, the lognormal means for both the low and high strength populations of the electrocoated fibres were essentially unchanged with gauge length. Changes were also indicated in the number and severity of surface flaws, caused by concurrent electrochemical processes.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00553446
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  • 6
    Electronic Resource
    Electronic Resource
    A bimodal lognormal model of the distribution of strength of carbon fibres: effects of electrodeposition of titanium di (dioctyl pyrophosphate) oxyacetate (1986)
    Springer
    Journal of materials science 21 (1986), S. 3912-3920 
    Details
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The tensile strength distribution of Fortafil-3 carbon fibres of circular cross-section has been investigated at different gauge lengths. The unimodal Weibull, unimodal lognormal and bimodal lognormal models were tested. Estimating the model parameters by the method of maximum likelihood, and testing each model by the Kolmogorov-Smirnov goodness-of-fit statistic at prescribed levels of significance, it is found that the data for untreated unsized fibres fit a bimodal lognormal model best. The proportions of the low and high strength populations,p andq, respectively, did not show any well-defined trend with gauge length and had average values close to 0.5. But the lognormal mean for each population showed an increasing trend with decreasing gauge length. It is inferred thatp andq are, respectively, related to the presence of surface flaws and internal defects, both of which probably have the same structural origin. After electrodeposition of titanium di (dioctyl pyrophosphate) oxyacetate (TDPO), the fibre strength was still best approximated by a bimodal lognormal distribution. But the weighting factorp for the weak population was reduced markedly, with a corresponding increase ofq, indicating the healing of surface flaws during electrodeposition of a protective layer of TDPO. Furthermore, in contrast to the observations with untreated fibres, the lognormal means for both the low and high strength populations of the electrocoated fibres were essentially unchanged with gauge length. Changes were also indicated in the number and severity of surface flaws, caused by concurrent electrochemical processes.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02431629
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  • 7
    Electronic Resource
    Electronic Resource
    Electroinitiated polymerization and copolymerization of phenylacetylene (1979)
    Springer
    Polymer bulletin 1 (1979), S. 785-791 
    Details
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary A linear conjugated polymer [(C6H5C=CH)] n, with a trans rich, cis-trans copolymer structure results from the electropolymerization of phenylacetylene.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00256280
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  • 8
    Electronic Resource
    Electronic Resource
    Electroinitiated polymerization of benzonitrile (1979)
    Springer
    Polymer bulletin 1 (1979), S. 421-426 
    Details
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The electroinitiated polymerization of benzonitrile yields a linear conjugated polymer, {ie421-01}(C6H5)C=N{ie421-02}. An anionic mechanism of polymerization is indicated.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00284413
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  • 9
    Electronic Resource
    Electronic Resource
    Prediction of fibre strength at the critical length: a simulation theory and experimental verification for bimodally distributed carbon fibre strengths (1993)
    Springer
    Journal of materials science 28 (1993), S. 4489-4496 
    Details
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A computer simulation model of fragment distribution with respect to the fibre strength in a single-filament composite test is developed using the bimodal Weibull statistics. The predictions of the theory are examined with experimental results for AU carbon fibres coated by zirconium-n-propoxide or a zircoaluminate complex. Weibull analysis reveals a bimodal distribution of fibre strengths, in which the fractions of low- and high-strength populations vary with gauge length. It is seen that the simulation results are in good agreement with experimental data if the best fit model of strength distribution is applied. Thus, the use of a bimodal distribution term in the simulation theory yields a predicted strength at the critical length which is in good agreement with the results of extrapolation of experimental data, while the unimodal distribution term leads to overestimation of the strength.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01154961
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  • 10
    Electronic Resource
    Electronic Resource
    Electropolymerization of monomers on metal electrodes (1978)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 22 (1978), S. 65-87 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The use of electropolymerization to coat metal electrode surfaces with polymers formed in situ was investigated in detail. Electrolysis was carried out in a three-compartment cell with fritted disk separators such that polymerization occurred in the middle compartment only. Both anodic and cathodic reactions were utilized to form coating on pretreated metal surfaces. It was shown that polymerization occurred both by vinyl polymerization of olefin monomers as well as by ring-opening reactions of cyclic monomers. The factors that control the coating thickness, the morphology of the polymer deposit, and the adhesion of the polymer formed to the metal substrates were determined. It was found that the growth of the coating on electrode followed the chain polymerization kinetics to a considerable degree. However, increased current did not necessarily lead to increased coating thickness because it also led to increased early termination of growing polymer chains to form soluble low molecular weight products. Water, because of its high surface tension, encourages physical adsorption on metal surfaces of organic monomers dissolved in it. Thus, water was found to be unique as solvent for obtaining coatings with good adhesion to metal substrates. Coatings formed were analyzed by several methods including infrared spectroscopy. Several types of bonding, other than bond formation caused by polymerization reactions, were identified. Finally, the cyclization of polyacrylonitrile was observed when the coating was obtained on aluminum cathode during electrolysis of acrylonitrile-sodium nitrate-DMF solution.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1978.070220107
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