ISSN:
0001-1541
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
A mathematical model is presented to describe coking and activity characteristics of porous catalysts in supercritical reaction mixtures. These characteristics are determined by the way in which temperature and pressure affect the simultaneous physicochemical rate processes involving the effective diffusion of reactants in the pore, coke formation, and coke extraction. For a parallel coking reaction, the model predicts that when the reaction mixture density is isothermally increased from subcritical to low-to-moderate values, the ensuing higher reaction rates and restricted diffusion lead to pore-mouth plugging and decreased catalyst effectiveness factors. At dense supercritical conditions, however, the enhanced coke solubilities in the reaction mixture alleviate pore-mouth restrictions, resulting in a recovery of catalyst activity and increased effectiveness factors. The model predicts an optimum supercritical density at which catalyst activity is maintained at a maximum value. At smaller than optimum density values, the reaction rate is limited by coke extraction and at larger than optimum values, the rate is subject to pore diffusion limitations. These predictions are qualitatively consistent with reported experimental observations.
Additional Material:
11 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aic.690380706
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