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  • 1
    Publication Date: 2023-01-21
    Description: Closure of the Central American Seaway (CAS) and hydrology of the Caribbean Sea triggered Northern Hemisphere Glaciation and played an important role in the Pliocene to modern‐day climate re‐establishing the deep and surface ocean currents. New data on Mn/Ca obtained with femtosecond laser ablation inductively coupled plasma mass spectrometry on well‐preserved tests of the epibenthic foraminifer Cibicidoides wuellerstorfi and infaunal C. mundulus contribute to the interpretation of paleoenvironmental conditions of the Caribbean Sea between 5.2 and 2.2 Ma (million years) across the closure of the CAS. Hydrothermal activity at the Lesser Antilles may be a primary source of Mn in the well‐oxygenated Plio‐Pleistocene Caribbean Sea. Incorporation of Mn in the benthic foraminifer shell carbonate is assumed to be affected by surface ocean nutrient cycling, and may hence be an indicator of paleoproductivity.
    Description: Plain Language Summary: The closure of the Panama Isthmus caused the expansion of ice sheets in the Northern Hemisphere and changed the water current dynamics and climate in the Caribbean Sea since the Pliocene (∼5.3 million years ago). New Mn/Ca data measured using femtosecond laser ablation inductively coupled plasma mass spectrometry on the deep‐sea benthic foraminifer species Cibicidoides wuellerstorfi and Cibicidoides mundulus help us understand past environmental conditions of the Caribbean Sea prevailed between 5.2 and 2.2 million years ago. While manganese might be sourced from the surrounding hydrothermal vents, its incorporation in the foraminifer shell carbonate might be related to nutrient cycling and may indicate past biological productivity in the ocean.
    Description: Key Points: Femtosecond‐laser ablation inductively coupled plasma mass spectrometry provides a new approach on distinguishing Mn of the ontogenetic shell calcite from Mn of the authigenic coatings. Ontogenetic Mn within the foraminifer shell calcite may result from the regional nutrient cycle. Mn in the deep eastern Caribbean Sea may mainly derive from hydrothermal sources along the Antilles Island Arc.
    Description: MPIC
    Description: https://doi.org/10.17632/bps7nw7922.1
    Keywords: ddc:560 ; manganese ; Cibicidoides wuellerstorfi ; Cibicidoides mundulus ; Central American Seaway ; trace elements ; hydrothermal ; paleoproductivity
    Language: English
    Type: doc-type:article
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  • 2
    Publication Date: 2024-02-21
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The Mg/Ca of marine calcareous Planktic Foraminifera (PF) shells is commonly used for sea surface temperature reconstructions. However, compared to open marine environments, hypersaline (>40) oligotrophic seas have been shown to accommodate PF with higher Mg/Ca and divergent temperature to Mg/Ca relationships. To investigate influencing factors of PF Mg uptake in hypersaline regions, we measured the Mg/Ca of two flux‐dominating PF species, 〈italic〉Globigerinoides ruber albus〈/italic〉 and 〈italic〉Turborotalita clarkei〈/italic〉, derived from a monthly resolved time series of sediment traps in the Gulf of Aqaba, northern Red Sea as well as the corresponding temperature, salinity, and 〈italic〉p〈/italic〉H values. The PF exhibit elevated Mg/Ca which cannot be explained by post‐deposition or interstitial sediment diagenetic processes. 〈italic〉G. ruber albus〈/italic〉 displays Mg/Ca trends that strongly follow seasonal mixed layer temperature changes. Conversely, 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 Mg/Ca trends do not follow temperature but rather show significant Mg/Ca enrichment following mixing of the surface water column. We present a framework for incorporating elevated Mg/Ca into global Mg/Ca‐T calibrations for 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 and present a new Mg/Ca‐T calibration suitable for hypersaline marine environments.〈/p〉
    Description: Plain Language Summary: Past seawater temperature is reconstructed from the magnesium‐to‐calcium ratio (Mg/Ca) in the calcareous shells of a group of marine microplankton called foraminifera. Two foraminifer species, 〈italic〉Globigerinoides ruber albus〈/italic〉 and 〈italic〉Turborotalita clarkei〈/italic〉, are abundant in the Gulf of Aqaba, northern Red Sea, at year‐round high temperatures and salinities. The shells of these foraminifera have elevated Mg/Ca relative to other marine regions, and here, we explore the factors causing this. The Mg/Ca values of both 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 and 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 reflect the environmental conditions of the water column. For 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉, temperature and salinity appear to be factors responsible for the Mg/Ca trends and elevated values. We incorporate the new Mg/Ca data for 〈italic〉G〈/italic〉. 〈italic〉ruber albus〈/italic〉 to calibrate elevated Mg/Ca with temperature for high‐salinity (>40) marine environments. The Mg/Ca of the deeper dwelling 〈italic〉T〈/italic〉. 〈italic〉clarkei〈/italic〉 show higher ratios following deep mixing of the surface water column and may indicate annually recurring phytoplankton blooms caused by nutrient input into the sunlit ocean surface.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉A new Mg/Ca temperature calibration for high salinity environments is presented for 〈italic〉Globigerinoides ruber albus〈/italic〉〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉A framework for incorporating high salinity environments into global Mg/Ca‐T calibrations is provided〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Enhanced Mg/Ca in subsurface dwelling 〈italic〉Turborotalita clarkei〈/italic〉 may indicate seasonal deep mixing of the upper water column〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: Israel Science Foundation http://dx.doi.org/10.13039/501100003977
    Description: Minerva PhD Fellowship Stipend
    Description: Advance School for Environmental Studies
    Description: https://doi.org/10.1594/PANGAEA.959629
    Description: https://doi.org/10.17617/3.EXFQC2
    Keywords: ddc:551.9 ; Gulf of Aqaba ; Planktic Foraminifera shells ; Mg/Ca ; sea surface temperature reconstructions
    Language: English
    Type: doc-type:article
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  • 3
    ISSN: 1749-6632
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Natural Sciences in General
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0014-5793
    Keywords: Actin ; Anisotonicity ; Cell swelling ; Cell volume ; Cytoskeleton ; Gene expression ; Glutamine ; Hypertonic ; Hypotonic ; Insulin ; Isolated hepatocyte
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0022-0248
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Journal of Crystal Growth 124 (1992), S. 377-382 
    ISSN: 0022-0248
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Journal of Crystal Growth 124 (1992), S. 389-394 
    ISSN: 0022-0248
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 7 (1982), S. 413-416 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The meander model of polymer melts assumes nearly parallel packing of molecular chains and therefore invites to describe shear deformation processes by “dislocation” motion in analogy to metals. Examination of the glass relaxation data for 12 amorphous polymers leads to reasonable values for the energy and the Burgers vector of segment dislocations which are also consistent with thermal properties of the glass transition.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 258 (1980), S. 300-313 
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Summary The dielectric relaxation behaviour of Polyglycine, Polyalanine, Nylon 3 and Nylon 4 has been measured in the frequency range from 10−3 Hz to 107 Hz within temperatures between −100 °C and 220 °C. Theγ 1-process ist observed in Nylon 3 and Nylon 4 but not in Polyglycine and Polyalanine. Therefore, at least two CH2-groups in the backbone chain are necessary for this process which is ascribed to the kink motion of C2H4-groups. Theγ 2 process appears in all substances and is explained by the kink motion of peptide groups with only one hydrogen bond to neighbouring chains. The influence of water content is discussed. Kink motion involving rotation of the peptide bond is responsible for theγ 3 process. This motion is not possible in Polyalanine because of the steric hindrance by the CH3 side group. In the temperature region between 170° and 220 °C the glass transition of the amorphous phase is observed. The cristallinity can be calculated from the relaxation strength.
    Notes: Zusammenfassung Das dielektrische Relaxationsverhalten von Polyglycin, Polyalanin, Nylon 3 und Nylon 4 wurde im Frequenzbereich von 10−3 bis 107 Hz und im Temperaturbereich von −100 °C bis + 220 °C untersucht. Derγ 1-Prozeß, der in der Literatur der Bewegung innerhalb der CH2-Sequenzen zugeordnet wird, wird in Nylon 3 und Nylon 4 beobachtet, nicht aber in Polyglycin und Polyalanin. Dies bedeutet, daß für diesen Prozeß mindestens zwei CH2-Gruppen in der Hauptkette notwendig sind, deren Bewegung dann als Kinkumlagerung von C2H4-Gruppen interpretiert wird. Derγ 2-Prozeß, der in allen untersuchten Substanzen auftritt, wird der Kinkbewegung von Peptidgruppen zugeordnet, die nur über eine Wasserstoffbrücke mit Nachbarketten verbunden sind. Der Einfluß des Wassergehalts der Proben wird diskutiert. Imγ 3-Prozeß kommen vermutlich Kinkumlagerungen mit Drehungen um die Peptidbindung vor. Bei Polyalanin ist diese Bewegung wegen der sterischen Behinderung durch die CH3-Gruppe nicht möglich. Bei Temperaturen zwischen 170 °C und 220 °C beobachtet man den Glasübergang der amorphen Phase. Die Kristallinität der Proben läßt sich aus der RelaxationsstärkeΔɛ bestimmen.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 263 (1985), S. 873-878 
    ISSN: 1435-1536
    Keywords: Dielectric measurements ; high pressure ; glass relaxation ; poly(vinyl acetate) ; poly(vinyl chloride)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Measurements of the complex relative permittivity of poly(vinyl acetate) from 35 °C to 190 °C and poly(vinyl chloride) from 90 °C to 150 °C in the frequency range 10−2 −107 Hz and the pressure range 1–5000 bar are reported. Details of the pressure generating system and of the dielectric equipment are described.
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