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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 2 (1970), S. 157-166 
    ISSN: 0538-8068
    Keywords: Chemistry ; Physics Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics and absolute rate constants for the free-radical chain reaction of tri-n-butyltin hydride with di-t-butyl disulfide have been measured in cyclohexane at 30°. The rate controlling step for chain propagation involves the cleavage of the disulfide bond by an attacking tributyltin radical. The rate constant for this bimolecular homolytic substitution at sulfur is ∼8 × 104 Mole-1 sec-1. Chain termination involves the self-reaction of two tributyltin radicals.The rate constants for attack of tributyltin radicals on some other disulfides and on elemental sulfur have also been measured. The results are compared with literature data for homolytic substitutions on these compounds by a variety of radicals which have their unpaired electron centered on carbon.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2019
    Description: Abstract Suprathermal electron bursts (STEBs), characterized by a board energy spectrum and a field‐aligned pitch angle distribution, have been well recognized to be associated with electron acceleration by inertial Alfvén waves and are thus conventionally termed as “Alfvénic aurora.” In this study, we report joint Enhanced‐Polar‐Outflow‐Probe (e‐POP) and ground‐based optical observations of Alfvénic auroras. In particular, we highlight the prominence of 630‐nm red line emissions under low‐energy Alfvénic auroral precipitation. During the event interval, e‐POP traverses two arcs. One bright arc dominated by green line emissions is clearly seen by all optical instruments; it is embedded in upward field‐aligned currents (FACs) yet leaves little imprint on the e‐POP suprathermal electron imager (SEI), likely due to that the precipitation is well above the upper energy limit of SEI. On the other hand, there is a red line arc that is pronounced only in 630‐nm images. Such a red‐line‐only arc is located in a transition from large‐scale upward FACs to downward FACs and is associated with a prominent STEB structure detected by e‐POP SEI. The STEB features an inverse energy time dispersion, namely, that lower‐energy electrons are seen earlier while higher‐energy electrons appear later. The red‐line‐only arc and its separation from the green line arc evolve in a repeatable fashion, each stemming from a poleward auroral intensification (PAI) propagated from higher latitudes. Following each poleward auroral intensification the green line arc progressively moved southward, while the red‐line‐only arc is quasi‐stationary and stayed relatively stable in latitude. We propose tentative interpretations of the above features based upon stationary inertial Alfvén waves.
    Print ISSN: 2169-9380
    Electronic ISSN: 2169-9402
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 3
    Publication Date: 2011-07-07
    Description: The azimuthal plasma pressure gradient in the near-Earth plasma sheet makes crucial contributions to field-aligned current (FAC) formation. Numerical simulations and statistical observations have shown that a plasma pressure peak tends to build up in the premidnight region of the near-Earth plasma sheet during the substorm growth phase owing to enhanced magnetic drift. This leads to azimuthal pressure gradients in this region. The temporal variation of the azimuthal pressure gradient may provide an indication for the FAC variations associated with the substorm growth phase and may set up a plasma sheet precondition for the substorm onset being triggered near this region. We take advantage of two of the Time History of Events and Macroscale Interactions during Substorms (THEMIS) spacecraft separated azimuthally near the orbit apogee and investigate the azimuthal plasma pressure gradient before substorm onset in the R ∼10–12 RE region. Equatorial plasma pressure is estimated by removing the curvature force effect. Five events with the spacecraft footprints mapped very close to the aurora onset region were selected. These events show substantial duskward pressure gradient enhancement 1–5 min before onset. The onset arc, which results from enhanced energetic electron precipitation, was found to intensify simultaneously with the pressure gradient enhancement before onset breakup occurs. Since the energy and energy flux of precipitating electrons reflect the upward FAC strength, these results indicate that the duskward azimuthal pressure gradient enhancement is associated with enhanced upward FAC during the late growth phase and leads to the intensification of the onset auroral arc soon before it breaks up. It is possible that this pressure gradient enhancement may lead to ballooning mode instability and thus substorm onset along the intensifying arc.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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