ISSN:
1573-9171
Keywords:
nitrile oxide
;
(dimorpholinophosphoryl)carbonitrile oxide
;
structure
;
chemical stability
;
X-ray diffraction study
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract An X-ray diffraction study of (dimorpholinophosphoryl)carbonitrile oxide (1) was carried out. The structure of the nitrile oxide group in compound1 is more similar to that in fulminic acid (HC≡N→O) than to those in aryl- and hetarylcarbonitrile oxides. The N→O bond in1 is shorter than those in the latter compounds, and the nitrile oxide fragment is more linear due to an increase in the XCN angle.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00698239
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