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Vulcanization of butyl rubber by p-quinone dioxime (1977)

Gan, L. M. ; Soh, G. B. ; Ong, K. L.

New York, NY [u.a.] : Wiley-Blackwell

Journal of Applied Polymer Science 21 (1977), S. 1771-1781

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ISSN: 0021-8995

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: The vulcanization of butyl rubber by p-quinone dioxime oxidized by red lead and tetrachloroquinone was investigated. The maximum physical effective crosslinking density of the vulcanizates appeared to be when p-quinone dioxime and the oxidizing agent were equimolar. The formation of one physical effective crosslink required one molecule of p-quinone dioxime. Chemical reactions are suggested for the vulcanization steps.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/app.1977.070210705

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