Electronic Resource
Oxford [u.a.]
:
International Union of Crystallography (IUCr)
Acta crystallographica
57 (2001), S. 139-140
ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The crystal structure of tricaesium cobalt pentachloride has been determined by X-ray diffraction at 10 K. The Co atom is at a site with {\overline 4}2m symmetry, one Cs atom is at a site with 42 symmetry, the other has mm site symmetry, one Cl ligand has 4/m symmetry and the other has m symmetry. The accurate and extensive data set collected should be suitable for charge–density analysis studies. In the CoCl42− ion, as the temperature is lowered, the Co—Cl bond length increases a little and the small distortion of the tetrahedron (site symmetry \overline 42m) is slightly reduced.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270100017297
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