ALBERT — All Library Books, journals and Electronic Records Telegrafenberg

Hits per page

hit 1 - 1 | 1 hit

Sorting

Electronic Resource

Dioxirane Epoxidation of α,β-Unsaturated Ketones (1991)

Adam, Waldemar ; Hadjiarapoglou, Lazaros ; Smerz, Alex

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 227-232

add to mindlist on the mindlist

Details

ISSN: 0009-2940

Keywords: Epoxidation ; Dioxiranes ; Ketones, α,β-unsaturated ; (E)-Chalcones ; (E)-2′-Hydroxychalcones ; 2-Cycloen-1-ones ; Caroate ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The synthesis of epoxides 3a - r is achieved in excellent yields by reaction of the α,β-unsaturated ketones 1a-c, 4,4′-disubstituted (E)-chalcones 1d-o, and 2′-hydroxy-4-substituted (E)-chalcones 1p - r with isolated dimethyldioxirane (2a) (as acetone solution) and/or in situ generated ethyl(methyl)dioxirane (2b). This method constitutes a useful alternative to the Weitz-Scheffer epoxidation (alkaline H2O2) of such electronpoor substrates.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19911240134

Permalink

	Location	Call Number	Expected	Availability

Others were also interested in ...

Paper (German National Licenses)

Fulltext

hit 1 - 1 | 1 hit