ISSN:
0268-2605
Keywords:
organosilane
;
α-alkyl-α-aminosilane
;
metalation
;
hydrosilylation
;
rearrangement
;
Brook
;
Chemistry
;
Industrial Chemistry and Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The readily available aminomethylsilanes can be utilized to prepare the less available α-alkyl-α-aminosilanes. Versatile t-butoxy-carbonal (Boc) derivatives can be metalated between nitrogen and silicon, and then alkylated by an electrophile at this position. Two alternative procedures were also developed, including an aza-reverse-Brook rearrangement of metalated N-silylcarbamates and hydrosilylation of N-alkenylcarbamates. © 1997 by John Wiley & Sons, Ltd.
Additional Material:
18 Ill.
Type of Medium:
Electronic Resource
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