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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 26 (1993), S. 2346-2360 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Langmuir 10 (1994), S. 334-339 
    ISSN: 1520-5827
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 88 (2000), S. 2956-2966 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Adhesively bonded elastic layers with thicknesses that are small relative to their lateral dimensions are used in a wide variety of applications. The mechanical response of the compliant layer when a normal stress is imposed across its thickness is determined by the effects of lateral constraints, which are characterized by the ratio of the lateral dimensions of the layer to its thickness. From this degree of confinement and from the material properties of the compliant layer, we predict three distinct deformation modes: (1) edge crack propagation, (2) internal crack propagation, and (3) cavitation. The conditions conductive for each mode are presented in the form of a deformation map developed from fracture mechanics and bulk instability criteria. We use experimental data from elastic and viscoelastic materials to illustrate the predictions of this deformation map. We also discuss the evolution of the deformation to large strains, where nonlinear effects such as fibrillation and yielding dominate the failure process. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 4458-4460 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Transmission electron microscopy was used to analyze the effects of annealing treatments on the morphologies of discontinuous gold films evaporated onto polystyrene or poly(2-vinylpyridine) substrates. For polystyrene substrates the average size of discrete gold particles increases significantly during a long-term annealing treatment at 179 °C. The size distribution is well approximated by a log normal distribution function, consistent with a coalescence mechanism for particle growth. The fluid character of the polymer substrates at the annealing temperature of interest allows us to control this coalescence rate, thereby providing a unique method for controlling the microstructure of discontinuous metal films. Cross-sectional transmission electron microscopy showed that the coalescence rate for gold particles in a poly(2-vinylpyridine) matrix is much less than the coalescence rate for gold particles in a polystyrene matrix, indicating that polymer/metal interactions play an important role in the determination of the coalescence rate.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 94 (1991), S. 5723-5738 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A detailed self-consistent field theory is used to calculate the properties of end-adsorbed polymer chains, or polymer "brushes,'' in equilibrium with a blend of adsorbing B polymer and nonadsorbing A polymer. The brush properties depend on χab, Na/Nb and β, where χab is the Flory interaction parameter characterizing the thermodynamic interaction between the A and B polymers, Na and Nb are the respective degrees of polymerization of the A and B polymers and kBTβ is the net attractive interaction between the adsorbing chain end and the surface. For χab=0, β(very-much-greater-than)1 and Na/Nb(very-much-greater-than)1 an asymptotic limit is reached where the brush properties are completely specified by z*/Rbg, where z* is the integrated surface excess of the adsorbing polymer and Rbg is its unperturbed radius of gyration. In this strong adsorption, dry brush regime the volume fraction of adsorbing polymer at the surface increases rapidly from 0.0 to 0.96 as z*/Rbg increases from 0.0 to 1.6. For z*/Rbg〉1.6 the surface volume fraction of the adsorbing polymer is close to one and the brush profiles are accurately described by a hyperbolic tangent form where the only adjustable parameter is a width parameter describing the interpenetration of the brush and the matrix polymer. This width decreases from 2Rbg at z*/Rbg=1.6 to 1.6Rbg at z*/Rbg=3.3. For high values of Na/Nb there is an attractive interaction between opposing polymer brushes, or between a single polymer brush and a nonadsorbing surface, which can be attributed to the free energy associated with the distortion of the matrix chains adjacent to the brush. Results are also extended to cases of weak adsorption characterized by low values of β.
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 2095-2104 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The properties of the interface between polystyrene (PS) and a random copolymer of polystyrene and poly(parahydroxystyrene) (PPHS) were modified by addition of a diblock copolymer of deuterated polystyrene (dPS) and poly(2-vinylpyridine) (PVP). Segregation of diblock copolymer chains to the interface between the immiscible blend components is driven by the compatibility of the dPS block with the PS phase and by a strong favorable interaction between the PVP block and the PPHS units of the random copolymer. Forward recoil spectrometry was used to measure the equilibrium excess of copolymer chains at the interface as a function of the copolymer volume fraction in the bulk PS phase. A dramatic increase in the interfacial adsorption is identified with the formation of emulsified "droplet'' phases which appear when the interfacial free energy between the immiscible blends becomes vanishingly small. Dynamic secondary-ion mass spectrometry was used to characterize these emulsified phases, and to verify our picture of the copolymer adsorption process. Comparison to predictions from a detailed self-consistent-field theory gives an estimate for the magnitude of favorable interaction between PVP and the PS/PPHS copolymer ((approximately-equal-to) 0.16kBT per repeat unit) and the magnitude of the interfacial tension between the two phases in the absence of a diblock copolymer ((approximately-equal-to)2 dyn/cm).
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new ceramic processing method, thermoreversible gelcasting (TRG), has been developed. The method uses a gelation process that can be reversed multiple times. Two Al2O3 systems have been explored with the use of a specific triblock copolymer to form a binding gel network. The mixture becomes a free-flowing liquid on heating above 60°C. However, on cooling below 60°C, the slurry instantaneously transforms to a physical gel. This process can be reversed easily (essentially with an infinite processing time window) while the solvent is present in the system, which is advantageous when trying to produce high-quality dense pieces if initial casting irregularities occur. Near-theoretically dense specimens have been produced with properties consistent with reported values of high-density Al2O3.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 25 (1992), S. 2122-2133 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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