ISSN:
1600-5368
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The AgI complex of 2,2′,3,3′-tetrahydro-4,4′-dithia-1,1′-binaphylidene (ttp) has been synthesized and its molecular structure determined as its PF6− salt, i.e. (2,2′,3,3′-tetrahydro-4,4′-dithia-1,1′-binaphylidene)silver(I) hexafluorophosphate, [Ag(C18H16S2)]PF6. The AgI ion has a distorted linear geometry comprised of the two S atoms of ttp, with an Ag—S distance of 2.4889 (8) Å and an S—Ag—S angle of 157.48 (4)°; the cation has twofold symmetry. This coordination mode results in the formation of a nine-membered ring.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S1600536801007759
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