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  • 1
    Publication Date: 2023-06-27
    Keywords: 92-597B; 92-597C; Aluminium oxide; Atomic emission spectroscopy (AES); Barium; Boron; Calcium oxide; Chromium; Cobalt; Copper; Deep Sea Drilling Project; Description; DRILL; Drilling/drill rig; DSDP; Event label; Gallium; Glomar Challenger; Iron oxide, Fe2O3; Leg92; Lithium; Magnesium oxide; Manganese oxide; Nickel; Phosphorus pentoxide; Potassium oxide; Rubidium; Sample code/label; Scandium; Silicon dioxide; Sodium oxide; South Pacific; Spectrophotometry; Strontium; Titanium dioxide; Total; Vanadium; Yttrium; Zinc
    Type: Dataset
    Format: text/tab-separated-values, 353 data points
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  • 2
    Publication Date: 2023-06-27
    Keywords: 92-597B; 92-597C; Deep Sea Drilling Project; Description; DRILL; Drilling/drill rig; DSDP; Event label; Glomar Challenger; Leg92; Mineral name; Sample code/label; South Pacific
    Type: Dataset
    Format: text/tab-separated-values, 36 data points
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  • 3
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    PANGAEA
    In:  Supplement to: Berndt, Michael; Seyfried, William E (1986): B, Li, and associated trace element chemistry of alteration minerals, Holes 597B and 597C. In: Leinen, M; Rea DK; et al. (eds.), Initial Reports of the Deep Sea Drilling Project, Washington (U.S. Govt. Printing Office), 92, 491-497, https://doi.org/10.2973/dsdp.proc.92.130.1986
    Publication Date: 2023-05-12
    Description: B, Li, and other trace elements were analyzed in samples from 12 celadonite and smectite-rich veins from oxidative and non-oxidative alteration zones in basalts from Holes 597B and 597C. The oxidative alteration zones are characterized by celadonite and Fe-oxyhydroxide and conspicuously high K, Rb, and B concentrations. In contrast, the non-oxidative alteration zones are characterized by Mg-rich smectite (saponite), talc, and calcite and high Li concentrations. Neither B nor Li reaches high concentrations in high-Al high-Ti veins that appear to have formed by replacement of basalt. B, Li, and Rb enrichments in vein assemblages of low-temperature origin reflect an important removal mechanism from seawater for these species. The alteration zones characterized by Mg-smectite and talc are strikingly enriched in Ni. There is a correlation between the Ni-enriched smectite and the presence of olivine in the host basalt; the correlation indicates that olivine alteration may be the source of the Ni. Other transition elements, including Cr, Mn, Co, Cu, and Zn, are often found in significant concentrations in the celadonite and high-Mg smectite veins, but their enrichments are neither as large nor as consistent as the enrichment of Ni in the Mg-smectite veins. Two high-Al, high-Ti vein assemblages of smectite and noncrystalline phases have transition element abundances similar to those of the host basalts but are relatively depleted in Cu and Cr. The material in these veins may have formed by replacement with concomitant release of Cu and Cr to circulating aqueous fluids.
    Keywords: Deep Sea Drilling Project; DSDP
    Type: Dataset
    Format: application/zip, 2 datasets
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 25 (1996), S. 421-433 
    ISSN: 1572-8927
    Keywords: Hydrogen ; gold ; hydrogen sensor ; Henry's law constant ; supercritical fluid ; yttrium stabilized zirconia membrane (YSZ)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Potentiometric studies of the Au-YSZ(Hg/HgO) (YSZ=yttrium stabilized zirconia) cell were conducted to investigate the suitability of gold as a sensing element forin situ determination of dissolved H2 in aqueous fluids at 375–400°C and 400 bars. Experimental results indicate that the gold electrode responds rapidly and reversibly to variations in dissolved H2, even at H2〈0.1 mmol-kg−1. Nernstian response of the cell to dissolved H2 was demonstrated at 400°C and 400 bars $$\Delta E = 0.9815 + 0.0668 \log m_{H_2 } $$ In fact, the performance of the gold electrode compares well to that of platinum. Considering the well known difficulties of using platinoid metals in H2S-bearing fluids, however, the gold electrode holds great promise forin situ measurement of dissolved H2 in chemically complex natural hydrothermal fluids. The results also suggest that the Au-YSZ(Hg/HgO) cell can be used to determine the solubility behavior of H2 in aqueous fluid at temperatures and pressures in the vicinity of the critical point of water. At present, such data are lacking, which severely constrains knowledge of the effect of temperature and pressure on the Henry's law constant of H2 in water.
    Type of Medium: Electronic Resource
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  • 5
    Publication Date: 2021-05-11
    Description: The isotopic composition of methane is of longstanding geochemical interest, with important implications for understanding petroleum systems, atmospheric greenhouse gas concentrations, the global carbon cycle, and life in extreme environments. Recent analytical developments focusing on multiply substituted isotopologues (‘clumped isotopes’) are opening a valuable new window into methane geochemistry. When methane forms in internal isotopic equilibrium, clumped isotopes can provide a direct record of formation temperature, making this property particularly valuable for identifying different methane origins. However, it has also become clear that in certain settings methane clumped isotope measurements record kinetic rather than equilibrium isotope effects. Here we present a substantially expanded dataset of methane clumped isotope analyses, and provide a synthesis of the current interpretive framework for this parameter. In general, clumped isotope measurements indicate plausible formation temperatures for abiotic, thermogenic, and microbial methane in many geological environments, which is encouraging for the further development of this measurement as a geothermometer, and as a tracer for the source of natural gas reservoirs and emissions. We also highlight, however, instances where clumped isotope derived temperatures are higher than expected, and discuss possible factors that could distort equilibrium formation temperature signals. In microbial methane from freshwater ecosystems, in particular, clumped isotope values appear to be controlled by kinetic effects, and may ultimately be useful to study methanogen metabolism.
    Description: Published
    Description: 262-282
    Description: 6A. Geochimica per l'ambiente
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2010. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Geochimica et Cosmochimica Acta 75 (2011): 1594-1607, doi:10.1016/j.gca.2010.12.020.
    Description: Hydrothermal experiments were conducted to evaluate the kinetics of H2(aq) oxidation in the homogeneous H2-O2-H2O system at conditions reflecting subsurface/near-seafloor hydrothermal environments (55-250 oC and 242-497 bar). The kinetics of the water-forming reaction that controls the fundamental equilibrium between dissolved H2(aq) and O2(aq), are expected to impose significant constraints on the redox gradients that develop when mixing occurs between oxygenated seawater and high- temperature anoxic vent fluid at near-seafloor conditions. Experimental data indicate that, indeed, the kinetics of H2(aq)-O2(aq) equilibrium become slower with decreasing temperature, allowing excess H2(aq) to remain in solution. Sluggish reaction rates of H2(aq) oxidation suggest that active microbial populations in near-seafloor and subsurface environments could potentially utilize both H2(aq) and O2(aq), even at temperatures lower than 40 oC due to H2(aq) persistence in the seawater/vent fluid mixtures. For these H2-O2 disequilibrium conditions, redox gradients along the seawater/hydrothermal fluid mixing interface are not sharp and microbially-mediated H2(aq) oxidation coupled with a lack of other electron acceptors (e.g. nitrate) could provide an important energy source available at low-temperature diffuse flow vent sites. More importantly, when H2(aq)-O2(aq) disequilibrium conditions apply, formation of metastable hydrogen peroxide is observed. The yield of H2O2(aq) synthesis appears to be enhanced under conditions of elevated H2(aq)/O2(aq) molar ratios that correspond to abundant H2(aq) concentrations. Formation of metastable H2O2 is expected to affect the distribution of dissolved organic carbon (DOC) owing to the existence of an additional strong oxidizing agent. Oxidation of magnetite and/or Fe++ by hydrogen peroxide could also induce formation of metastable hydroxyl radicals (•OH) through Fenton-type reactions, further broadening the implications of hydrogen peroxide in hydrothermal environments.
    Description: This research was conducted with partial support from the NSF OCE-0752221 and the Geophysical Laboratory Postdoctoral Fellowship. We would also like to acknowledge contributions by the W.M. Keck Foundation and Shell towards supporting the hydrothermal lab at the Geophysical Lab. SMS acknowledges support from NSF OCE-0452333 and the Alfried-Krupp Wissenschaftskolleg Greifswald (Germany), while WES acknowledges support from NSF grants OCE-0549457 and OCE- 0813861.
    Keywords: Knallgas reaction ; H2 oxidation ; Metastable hydrogen peroxide ; Anaerobic chemolithoautotrophic metabolism ; Fenton reaction ; Hydrothermal systems
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: application/pdf
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  • 7
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Frontiers in Microbiology 6 (2015): 901, doi:10.3389/fmicb.2015.00901.
    Description: Many deep-sea hydrothermal vent systems are regularly impacted by volcanic eruptions, leaving fresh basalt where abundant animal and microbial communities once thrived. After an eruption, microbial biofilms are often the first visible evidence of biotic re-colonization. The present study is the first to investigate microbial colonization of newly exposed basalt surfaces in the context of vent fluid chemistry over an extended period of time (4–293 days) by deploying basalt blocks within an established diffuse-flow vent at the 9°50′ N vent field on the East Pacific Rise. Additionally, samples obtained after a recent eruption at the same vent field allowed for comparison between experimental results and those from natural microbial re-colonization. Over 9 months, the community changed from being composed almost exclusively of Epsilonproteobacteria to a more diverse assemblage, corresponding with a potential expansion of metabolic capabilities. The process of biofilm formation appears to generate similar surface-associated communities within and across sites by selecting for a subset of fluid-associated microbes, via species sorting. Furthermore, the high incidence of shared operational taxonomic units over time and across different vent sites suggests that the microbial communities colonizing new surfaces at diffuse-flow vent sites might follow a predictable successional pattern.
    Description: This work was partly supported by grants from the US National Science Foundation to SS (OCE-0452333, 1136727), to TS (OCE-0117117, 0525907, 0961186, 1043064, 0327261, 1131620), to WS and KD (1434798), as well as a grant by the WHOI Deep Ocean Exploration Institute to SB, TS, and SS.
    Keywords: Hydrothermal vents ; Colonization ; Species sorting ; Settlement ; Volcanic eruption ; 16S rRNA ; Epsilonproteobacteria ; Disturbance
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 8
    Publication Date: 2022-05-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Tao, C., Seyfried, W. E., Jr., Lowell, R. P., Liu, Y., Liang, J., Guo, Z., Ding, K., Zhang, H., Liu, J., Qiu, L., Egorov, I., Liao, S., Zhao, M., Zhou, J., Deng, X., Li, H., Wang, H., Cai, W., Zhang, G., Zhou, H., Lin, J., & Li, W. Deep high-temperature hydrothermal circulation in a detachment faulting system on the ultra-slow spreading ridge. Nature Communications, 11(1), (2020): 1300, doi:10.1038/s41467-020-15062-w.
    Description: Coupled magmatic and tectonic activity plays an important role in high-temperature hydrothermal circulation at mid-ocean ridges. The circulation patterns for such systems have been elucidated by microearthquakes and geochemical data over a broad spectrum of spreading rates, but such data have not been generally available for ultra-slow spreading ridges. Here we report new geophysical and fluid geochemical data for high-temperature active hydrothermal venting at Dragon Horn area (49.7°E) on the Southwest Indian Ridge. Twin detachment faults penetrating to the depth of 13 ± 2 km below the seafloor were identified based on the microearthquakes. The geochemical composition of the hydrothermal fluids suggests a long reaction path involving both mafic and ultramafic lithologies. Combined with numerical simulations, our results demonstrate that these hydrothermal fluids could circulate ~ 6 km deeper than the Moho boundary and to much greater depths than those at Trans-Atlantic Geotraverse and Logachev-1 hydrothermal fields on the Mid-Atlantic Ridge.
    Description: This work was supported by National Key R&D Program of China under contract no. 2018YFC0309901, 2017YFC0306603, 2017YFC0306803, and 2017YFC0306203, COMRA Major Project under contract No. DY135-S1-01-01 and No. DY135-S1-01-06.
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 9
    Publication Date: 2020-06-16
    Description: Since the initial discovery of low-temperature alkaline hydrothermal vents off the Mid-Atlantic Ridge axis nearly 20 y ago, the observation that serpentinizing systems produce abundant H2has strongly influenced models of atmospheric evolution and geological scenarios for the origin of life. Nevertheless, the principal mechanisms that generate H2in these systems, and how secular changes in seawater composition may have modified serpentinization-driven H2fluxes, remain poorly constrained. Here, we demonstrate that the dominant mechanism for H2production during low-temperature serpentinization is directly related to a Si deficiency in the serpentine structure, which itself is caused by low SiO2(aq) concentrations in serpentinizing fluids derived from modern seawater. Geochemical calculations explicitly incorporating this mechanism illustrate that H2production is directly proportional to both the SiO2(aq) concentration and temperature of serpentinization. These results imply that, before the emergence of silica-secreting organisms, elevated SiO2(aq) concentrations in Precambrian seawater would have generated serpentinites that produced up to two orders of magnitude less H2than their modern counterparts, consistent with Fe-oxidation states measured on ancient igneous rocks. A mechanistic link between the marine Si cycle and off-axis H2production requires a reevaluation of the processes that supplied H2to prebiotic and early microbial systems, as well as those that balanced ocean–atmosphere redox through time.
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
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  • 10
    Publication Date: 2018-09-11
    Description: Hydrothermal experiments were performed at elevated temperature (420–500 °C) and pressure (31.0–51.0 MPa) in the NaCl-H2O system to measure quartz solubility in coexisting vapor and liquid and extend the calibrated range of the Si-Cl geothermobarometer. In the vapor, the density-based equations for quartz solubility of Fournier (1983, http://doi.org/10.1016/0016-7037(83)90279-X) and Von Damm et al. (1991, http://doi.org/10.2475/ajs.291.10.977) agree well with the experimental data, while the equation of Fournier (1983) also accurately predicts SiO2(aq) concentrations in the liquid. Importantly, the equations of Fournier (1983) and Von Damm et al. (1991) were calibrated based on quartz solubility in single phase fluids (no coexisting vapor-liquid) at higher pressure than investigated here. The new experimental data therefore extend the pressure range of the density-equations and demonstrate that quartz solubility in either vapor or liquid can be treated independently as a function of temperature, pressure, and fluid density. The Si-Cl geothermobarometer indicates that fluids venting from Piccard reach 540 ± 15 °C, 62.5 ± 3.0 MPa. These are the hottest and deepest conditions yet recorded by an actively venting seafloor hydrothermal fluid. Based on the calculated enthalpy differences between the subsurface fluid and that venting at the seafloor, approximately one third of the heat extracted at depth is lost during conductive cooling of the hydrothermal fluid. Incorporating the heat lost during conductive cooling into the overall budget at Piccard yields a flux of 100 ± 37 MW and an associated hydrothermal fluid flux of 1.2 ± 0.4 × 109 kg/year. The newly calibrated Si-Cl geothermobarometer provides important constraints for accurate determination of heat and mass fluxes at axial vent sites. ©2018. American Geophysical Union. All Rights Reserved.
    Electronic ISSN: 1525-2027
    Topics: Chemistry and Pharmacology , Geosciences , Physics
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