ISSN:
0009-2940
Keywords:
Ionic ozonides
;
Ammonium ion, bisquaternary
;
C-H…O hydrogen bonds
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The bisquaternary ammonium ozonides Me3N+(CH2)n +NMe3(O3-)2 with n = 3, 4, 6 (1, 2, 3), Me3N+(CH2)3+NMe3(O3-)2 · 3 NH3 (1a), Me3N+(p-Ph)+NMe3(O3-)2 (4) and Me3N+(p-Ph)+NMe3(O3-)2 · NH3 (4a) were obtained in quantitative yields by cation exchange starting from CsO3. The compounds 1a and 3 have been studied by single crystal X-ray analysis. The influence of C-H…O and N-H…O hydrogen bonds on the bond length and the bond angle of the ozonide anion is discussed; earlier results are included. The difference between the two bond lengths within the O3- ion [137.4(3) pm and 129.5(3) pm] in 1a is unexpectedly large. Thermal stabilities determined by DTA/TG methods range from 24-83°C.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19961290904
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