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  • 1
    Publication Date: 2016-06-11
    Description: Al 2 O 3 /TiO 2 double layer anti-reflection coating (ARC) film formed by spray pyrolysis was introduced for monocrystalline silicon solar cells as the nonvacuum processing method. The thickness of the Al 2 O 3 layer and TiO 2 compact layer was controlled by the volume of deposited precursor solution and confirmed by ellipsometry and scanning electron microscope. The average photovoltaic properties of photocurrent density ( J sc ), the open-circuit photovoltage ( V oc ), the fill factor ( FF ), and the photo energy conversion efficiency ( η ) were 37.0 mA/cm 2 , 590 mV, 0.712, and 15.5%, respectively. A significant improvement on J sc and η could be confirmed owing to the Al 2 O 3 /TiO 2 ARC. According to the results of Fourier transform infrared (FTIR) spectroscopy and optical simulation with modeling for the reflectance properties, it was confirmed that C-H-based organics remained after the deposition of thin films. Al 2 O 3 /TiO 2 double layer anti-reflection coating film formed by spray pyrolysis was introduced for monocrystalline silicon solar cells as a nonvacuum processing method. According to the results of Fourier transform infrared spectroscopy and optical simulation with modeling for the reflectance properties, it was confirmed that C-H-based organics remained after the deposition of thin films.
    Electronic ISSN: 2050-0505
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by Wiley
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  • 2
    Publication Date: 2016-09-07
    Description: Due to the high conversion efficiency, organic-inorganic hybrid perovskite (CH 3 NH 3 PbI 3 ) solar cells are investigated for new practical energy resources for our future society. However, the perovskite solar cells have been quite unstable devices. In this manuscript, the history of perovskite solar cells is introduced, and then, the efforts to improve and understand the stability issue of perovskite solar cells are summarized.
    Electronic ISSN: 2166-532X
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 3
    Publication Date: 2015-02-19
    Description: Screen-printing aluminum is still dominantly used in the solar cell fabrication process. Ethyl cellulose is one of the main contents of screen-printing pastes that require dichloromethane for its cleaning process, a substance renowned for being extremely toxic and threatening to the human body. Developing environmental friendly aluminum pastes is essential in order to provide an alternative to the commercial pastes. In this work, new, nontoxic polyvinyl alcohol-based aluminum pastes are introduced. Polyvinyl alcohol was used as a soluble polymer that can be synthesized without saponification and that is also soluble in water. Three different pastes were developed using different recipes including many aluminum particle sizes varying from 3.0 to 45 μm, aluminum oxide with particle sizes between 35 and 50 μm, and acetic acid. Evaluation of the pastes was carried out by Scanning Electron Microscope (SEM) image analysis, sheet resistance measurements, and fabricating silicon solar cells using each paste. Solar cells with 15.6% efficiency were fabricated by nonvacuum processing on CZ-Si p-type wafers using developed aluminum pastes on the back side.
    Print ISSN: 1110-662X
    Electronic ISSN: 1687-529X
    Topics: Electrical Engineering, Measurement and Control Technology , Energy, Environment Protection, Nuclear Power Engineering
    Published by Hindawi
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  • 4
    Publication Date: 2012-06-11
    Description: CuInSe 2 powders synthesized by ball milling were printed on In 2 S 3 /TiO 2 /FTO/glass substrates, resulting in superstrate solar cells.  Although particle structure of CuInSe 2 in the layer remained after heating at 600 °C under N 2 gas, photovoltaic effects were observed; the open-circuit voltage and short-circuit current density were 0.45 V and 5.6 mA/cm 2 , respectively.  The effects of annealing time on the structural, optical and photovoltaic properties of CuInSe 2 were studied by scanning electron micrograph (SEM), X-ray diffraction (XRD), t hermogravimetric analysis (TGA) and UV-Vis reflectance absorption spectroscopy.  The CuInSe 2 solar cells were printed in air ambient without vacuum processing and without toxic and explosive chemicals (e.g., hydrazine, H 2 Se and H 2 S), which can offer a promising strategy for future research and industrial investigation into cost-effective photovoltaic systems. Key words : Photovoltaic system; Photovoltaic effects; CuInSe 2 solar cells
    Electronic ISSN: 1923-8479
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by CSCanada
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  • 5
    Publication Date: 2014-05-06
    Description: Te and Se layers were deposited on 〈glass/FTO/flat-TiO2〉 by electrochemical deposition. The Te-Se-stacked layer was annealed at 200°C, and then, the migration of Te into the Se layer by annealing was confirmed using auger electron spectroscopy (AES), which was performed by Te doping on the Se layer. Au back contact was coated by vacuum deposition on the Te-doped Se layer, resulting in superstrate-structured solar cells of 〈glass/FTO/flat-TiO2/Se-doped Te/Au〉 with a 0.50 V open-circuit voltage, 6.4 mA/cm2 photocurrent density, 0.36 fill factor, and 1.17% conversion efficiency.
    Print ISSN: 1110-662X
    Electronic ISSN: 1687-529X
    Topics: Electrical Engineering, Measurement and Control Technology , Energy, Environment Protection, Nuclear Power Engineering
    Published by Hindawi
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  • 6
    Publication Date: 2011-12-23
    Description: Titania powder (P25) was dispersed by bead-milling breakdown method, and the dispersivity of TiO2 was controlled by adjusting the mean secondary TiO2 particle size to 45, 56, and 75 nm by changing the dispersion solvent blend ratio of ethanol and terpineol. The transparency of the coated layer increased when the particle size of TiO2 aggregates became smaller than 100 nm. Although the transparency was significantly different according to differences in the size of nanocrystallyne-TiO2 aggregates, the resulting photovoltaic (PV) effect of a dye-sensitized solar cell (DSSC) was not significantly different between the different aggregate sizes. A double layer structure (transparent TiO2 layer/opaque TiO2 layer) was adopted to improve the PV effect, which resulted in an improvement of the photocurrent and conversion efficiency of 13.2% and 11.1%, respectively, from that for the DSSCs with single-layered TiO2 electrodes.
    Print ISSN: 1110-662X
    Electronic ISSN: 1687-529X
    Topics: Electrical Engineering, Measurement and Control Technology , Energy, Environment Protection, Nuclear Power Engineering
    Published by Hindawi
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  • 7
    Publication Date: 2012-02-02
    Description: In order to improve the thermal durability of dye-sensitized solar cells, epoxy polymer was coated on dyed-TiO 2 electrode to prevent dye desorption under heating condition over 80 °C.  The covering effect on epoxy polymer was confirmed using impedance spectroscopy.  Using the epoxy polymer coating with Z907 Ru dye and ionic liquid electrolyte, the DSC photovoltaic durability was improved up to 90 °C, which is the highest temperature published for the DSC durability test.  Although the epoxy polymer suppressed the DSC photovoltaic effect, it enhance the thermal durability; DSC coated epoxy polymer on the dyed-TiO 2 electrode was able to prolong the efficiency over 90% of the initial value at 90 °C for 550 hours. Key words: Dye-sensitized solar cells; Epoxy polymer; Ionic liquid electrolyte; Thermal durability; Heat test
    Electronic ISSN: 1923-8479
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by CSCanada
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  • 8
    Publication Date: 2013-07-12
    Description: A double-bond-edged Ru dye (code name: SG1051) has been studied as a novel sensitizing dye for ultradurable dye-sensitized solar cells (DSCs). The SG1051 Ru dye showed the quick dye-uptake time (1 h for the optimized condition: , using volatile electrolyte) and the strong adsorption strength compared with standard Ru dyes (N719 and Z907), which was checked by successive dipping of dye-adsorbed nanocrystalline-TiO2 electrodes into NaOH aqueous. solution and acetonitrile. The resulting DSCs using SG1051 Ru dye and ionic-liquid electrolyte survived the durability test at 120°C for 480 h, which can be the strong interest of the industrial groups.
    Print ISSN: 1110-662X
    Electronic ISSN: 1687-529X
    Topics: Electrical Engineering, Measurement and Control Technology , Energy, Environment Protection, Nuclear Power Engineering
    Published by Hindawi
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  • 9
    Publication Date: 2013-07-08
    Description: Cu(In,Ga)S2 nanoparticles were synthesized by a hot-injection method under a low-vacuum ambience, which were printed and annealed with Se vapor for Cu(In,Ga)(S,Se)2 solar cells. The Cu(In,Ga)S2 nanoparticles were around 14 nm, and the stable ink was obtained by dispersing the nanoparticles in hexanethiol. The crystallinity of the Cu(In,Ga)(S,Se)2 films increased with the increase in annealing temperature. Cu(In,Ga)(S,Se)2 solar cells with KCN etching after annealing showed better photovoltaic properties than KCN etching before annealing and without etching. The best cell was observed at an annealing temperature of C and KCN etching after annealing; the parameters of this cell were a short-circuit photocurrent density of 27.12 mA/cm2, open-circuit voltage of 0.42 V, fill factor of 0.38, and conversion efficiency of 4.3%.
    Print ISSN: 1110-662X
    Electronic ISSN: 1687-529X
    Topics: Electrical Engineering, Measurement and Control Technology , Energy, Environment Protection, Nuclear Power Engineering
    Published by Hindawi
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  • 10
    Publication Date: 2016-08-16
    Description: A non-vacuum processing method for preparing polymer-based ZrO2/TiO2 multilayer structure antireflection coating (ARC) films for crystalline silicon solar cells by spin coating is introduced. Initially, ZrO2, TiO2 and surface deactivated-TiO2 (SD-TiO2) based films were examined separately and the effect of photocatalytic properties of TiO2 film on the reflectivity on silicon surface was investigated. Degradation of the reflectance performance with increasing reflectivity of up to 2% in the ultraviolet region was confirmed. No significant change of the reflectance was observed when utilizing SD-TiO2 and ZrO2 films. Average reflectance (between 300 nm–1100 nm) of the silicon surface coated with optimized polymer-based ZrO2 single or ZrO2/SD-TiO2 multilayer composite films was decreased down to 6.5% and 5.5%, respectively. Improvement of photocurrent density (Jsc) and conversion efficiency (η) of fabricated silicon solar cells owing to the ZrO2/SD-TiO2 multilayer ARC could be confirmed. The photovoltaic properties of Jsc, the open-circuit photo voltage (VOC), the fill factor (FF), and the η were 31.42 mA cm−2, 575 mV, 71.5% and 12.91%. Efficiency of the solar cells was improved by the ZrO2-polymer/SD-TiO2 polymer ARC composite layer by a factor of 0.8% with an increase of Jsc (2.07 mA cm−2) compared to those of fabricated without the ARC.
    Electronic ISSN: 1996-1073
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by MDPI Publishing
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