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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 2463-2479 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The viscoelastic melt behavior of poly(2,6-dimethyl-1,4-phenylene oxide) (PPOPPO is a registered trademark of the General Electric Company. resin), high-impact polystyrene (HIPS), and a 35-65 blend of these polymers has been characterized by measuring the steady shear viscosity and primary normal stress difference and the dynamic storage and loss moduli as functions of shear rate or frequency and temperature. Time-temperature superpositioning was used to generate master curves of each type of data for a reference temperature of 260°C. This procedure required five different empirical shift factors for each material. These shift factors show large differences between PPO resin and HIPS and exhibited large deviations from the WLF equation with universal constants. This result suggests that the temperature dependence of the relaxation processes in PPO resin is significantly different from the temperature dependence of HIPS relaxations. Flow activation energies computed from the viscosity data for PPO resin are much higher and more shear sensitive than those calculated for HIPS. The computed relaxation spectra clearly display the effect of long-time relaxation mechanisms associated with PPO molecules when compared to HIPS. The 35-65 blend exhibits general rheological compatibility with material parameters and responses intermediate between PPO resin and HIPS. This result is indicative of a high degree of segmental mixing for the two components in the blend.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 15 (1975), S. 51-62 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A second-generation apparatus was built and used to inflate heat-softened plastic sheets to shapes from hemispheres to large spheroidal bubbles. Three sheet materials, polystyrene, high-impact polystyrene, and cellulose acetate butyrate, were successfully formed beyond the hemispherical shape at temperatures somewhat below industrial levels. Four others, rigid poly-(vinyl chloride), an acrylic-modified PVC, cast poly(methyl methacrylate), and polycarbonate, could not be deformed beyond the hemispherical shape without rupture. Measurements included bubble profiles, thickness distributions and local extension ratios for the final bubbles; two plots of profile growth measured from high-speed motion pictures; and a continuous record of bubble temperatures and blowing pressure from which the meridional temperature distributions were plotted.Fifteen bubbles were measured and analyzed. Profiles and extension ratios were compared with those computed from the equations of isotropic, isothermal elasticity, using several different strain-energy functions with constant material parameters. Agreement over all fifteen bubbles on all properties was about ±10.8 percent (absolute) for the best models considered. Bubble growth occurred over periods of 5 to 8 seconds, with about 90 percent of the final area of the larger bubbles being generated in the final 1.5 seconds. The maximum areal elongations obtained were 18,600 percent for clear polystyrene at 238°F, 14,300 percent for high-impact polystyrene at 224°F, and 1,010 percent for cellulose acetate butyrate at 280°F.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 1978-12-01
    Print ISSN: 0148-6055
    Electronic ISSN: 1520-8516
    Topics: Physics
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