ISSN:
1040-7685
Keywords:
capillary electrophoresis
;
enantiomer separation
;
immobilized cyclodextrin
;
Chirasil-Dex
;
cyclodextrin derivatives
;
buffer additives
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
An immobilized chiral stationary phase, Chirasil-Dex, coated onto the inner surface of a 50 μm i.d. capillary and cyclodextrin derivatives added to the running buffer were simultaneously used for the study of enantiomer separations by capillary electrophoresis. Dependent on the cyclodextrin concentration in the mobile phase, a reversal of the elution order of enantiomers due to dual chiral recognition mechanisms was observed.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mcs.1220060109
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