ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Several acyl derivatives of poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) were obtained by Friedel - Crafts acylation, and the products were used to prepare membranes. During the pervaporation of 10% aqueous solutions of ethanol, acetone, 1-propanol, or dioxan, membranes made from unmodified, benzoylated, or propionylated PPO (glassy polymers, Tg 〉 200°C) were preferentially permeable to water, and their separation factors were mainly dependent on the molecular weight of the solvent. Membranes made from palmitoylated PPO (nonglassy polymer, Tg = 34.9°C) were preferentially permeable to organic solvents, and their separation factors correlated with the solubility parameters of the solvents under investigation. As regards membranes made from caproylated PPO (Tg = 130.6°C), there was no unambiguous relation to molecular weights of the solvents or to their solubility parameters. © 1992 John Wiley & Sons, Inc.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1992.070461012
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