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  • 1
    Publication Date: 2019-06-28
    Description: An unexpected and significant physico-chemical degradation of Coflon PVDF specimens was observed at the end of 1994 during routine scheduled exposure exercises on strained material. The intent was to age various samples, including some strained in a 4-point bend configuration, in methanol at 140 C and subsequently submit the aged samples to various tests including dynamic fatigue and fracture toughness. However, the samples deteriorated to such an extent that such testing was not possible: only when conditions were made less severe was it found possible to perform such testing. The purpose of the current report is to describe the nature of the PVDF deterioration observed during a number of tests performed to examine this phenomenon. This report also records, as Appendix 1, some SEM/X-ray microanalysis data on Coflon samples exposed to a methanol/amine mixture, and to other amine or H2S-aged samples.
    Keywords: Nonmetallic Materials
    Type: NASA/CR-95-207623 , NAS 1.26:207623 , CAPP/M.6
    Format: application/pdf
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  • 2
    Publication Date: 2019-07-10
    Description: This report deals with all recent mechanical testing performed on variously aged samples of Coflon and TefzeL to complete the work for Phase 1. Earlier results were reported in CAPP/M.7. Fluids A, F, G, and I have all been used for ageing in the last 12 month period, with particular attention concentrated on the effects of Fluid F as a result of discussions at the December 1995 steering committee meeting in Austin. Dramatic mechanical and physical changes occurred to Coflon in our initial studies after 4 weeks at 120 C in this sour gas mixture and so a detailed matrix was drawn up to investigate the effects of time and temperature of exposure. Subsequent tensile tests and compact tension (CT) fatigue tests were performed. Fatigue testing has been limited during this period to Coflon only; however, Tefzel CT samples have been exposed to the same conditions as the Coflon allowing the possibility for fatigue tests to be performed at a later date. Fluid A exposures during the last 6 months have been long-term at 65 C, 100 C and 120 C only. These exposures have been a continuation of earlier work and will complete the investigation of this fluid. Other chemical ageings have involved Fluid G at 120 C to confirm and investigate the hostile nature of this fluid on Coflon. Again, this fluid will not be used in Phase 2. Finally, long-term exposures in Fluid 1, a high aromatic oil mixture, were carried out to investigate the effects on the polymers of aromaticity in a simulated service fluid.
    Keywords: Nonmetallic Materials
    Type: NASA/CR-97-207626 , NAS 1.26:207626 , CAPP/M.12-Rev-A
    Format: application/pdf
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  • 3
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    In:  Jahresbericht / Hamburger Synchrotronstrahlungslabor HASYLAB am Deutschen Elektronen-Synchrotron DESY = Annual report
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
    Type: info:eu-repo/semantics/bookPart
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